Lesson 5.1.1
5.1.1 How fast Quiz: OCR Chemistry, Unit 4
20 questions
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Lesson 5.1.1, How fast: 20 multiple choice questions for the OCR Chemistry (H432), Unit 4: Physical chemistry and transition elements, written with Revision Ninja.
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The 20 questions
-
What is the overall order of a reaction whose rate equation is rate = k[A][B]^2?
- 3
- 2
- 5
- 1
-
What term describes the slowest step in a multi-step reaction mechanism?
- Rate-determining step
- Activation step
- Propagation step
- Overall reaction order
-
What are the units of the rate constant k for a reaction with rate = k[A]^2?
- mol dm^-3 s^-1
- s^-1
- dm^6 mol^-2 s^-2
- dm^3 mol^-1 s^-1
-
What term is the time taken for a reactant's concentration to decrease by half?
- Induction period
- Half-life
- Reaction order
- Rate constant
-
How does the half-life of a first-order reaction change as reactant concentration decreases?
- Decreases by half
- Increases continuously
- Doubles each time
- Remains constant
-
What is the shape of a concentration-time graph for a zero-order reactant?
- Upward sloping curve
- Downward straight line
- Exponential decay curve
- Horizontal straight line
-
A rate-concentration graph for a reactant is a horizontal straight line. What is the order with respect to that reactant?
- Zero order
- First order
- Second order
- Third order
-
A first order reaction has a half-life of 50 s. What is the rate constant k, to two significant figures?
- 0.035 s^-1
- 0.014 s^-1
- 1.4 s^-1
- 0.0069 s^-1
-
Reactant concentration falls from 1.00 mol dm^-3 to 0.50 mol dm^-3 in 40 s in a first order reaction. How long does it take to fall from 0.50 to 0.25 mol dm^-3?
- 20 s
- 40 s
- 80 s
- 10 s
-
Reactant concentration falls from 0.80 to 0.40 mol dm^-3 in a reaction. Over the 200 s interval the average rate is measured as the change over time. What is this average rate?
- 0.0040 mol dm^-3 s^-1
- 0.20 mol dm^-3 s^-1
- 0.00050 mol dm^-3 s^-1
- 0.0020 mol dm^-3 s^-1
-
Initial rate experiments show that doubling [A] doubles the rate and doubling [B] increases the rate four times. What is the rate equation?
- rate = k[A]^2[B]^2
- rate = k[A]^2[B]
- rate = k[A][B]
- rate = k[A][B]^2
-
For a reaction with rate = k[A][B]^2, the rate is 0.0032 mol dm^-3 s^-1 when [A] = 0.20 mol dm^-3 and [B] = 0.10 mol dm^-3. What is k?
- 0.625 mol^-2 dm^6 s^-1
- 1.6 mol^-2 dm^6 s^-1
- 1.6 s^-1
- 16 mol^-2 dm^6 s^-1
-
A first order reaction has rate constant k = 0.0462 s^-1. What is its half-life?
- 32.1 s
- 0.0327 s
- 15.0 s
- 7.5 s
-
In a clock reaction, what quantity is inversely proportional to the time measured?
- Activation energy
- Initial rate
- Rate constant
- Order of reaction
-
For rate = k[A][B], how many molecules of A feature in the rate-determining step?
- Two molecules
- Three molecules
- One molecule
- Zero molecules
-
A plot of ln k against 1/T for a reaction has a gradient of -4000 K. Using R = 8.31 J K^-1 mol^-1, what is the activation energy?
- 0.48 kJ mol^-1
- 33.2 kJ mol^-1
- 4000 kJ mol^-1
- 481 kJ mol^-1
-
A plot of ln k against 1/T has a gradient of -9.0 x 10^3 K. What is the activation energy, using R = 8.31 J K^-1 mol^-1?
- 74.8 kJ mol^-1
- 9.0 kJ mol^-1
- 748 kJ mol^-1
- 1.08 kJ mol^-1
-
What increases when temperature rises, causing the rate constant to increase?
- Frequency of collisions
- Overall enthalpy change
- Total activation energy
- Proportion exceeding Ea
-
Which equation is the Arrhenius equation?
- k = A e^(Ea/RT)
- k = ln 2 / t1/2
- k = A e^(-Ea/RT)
- rate = k[A]^m[B]^n
-
What is the shape of a rate-concentration graph for a second-order reactant?
- Upward curve
- Downward curve
- Horizontal line
- Sloping straight line
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