Lesson 4.2.4

4.2.4 Analytical techniques Quiz: OCR Chemistry, Unit 3

20 questions

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Lesson 4.2.4, Analytical techniques: 20 multiple choice questions for the OCR Chemistry (H432), Unit 3: Core organic chemistry, written with Revision Ninja.

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The 20 questions

  1. What effect does infrared radiation have on covalent bonds in molecules?

    • Ionise completely
    • Break heterolytically
    • Vibrate more
    • Rotate freely
  2. Which two absorption peaks in an IR spectrum identify a carboxylic acid?

    • C=O and C-H
    • C=C and O-H
    • O-H and C-N
    • C=O and O-H
  3. Which broad IR absorption peak is used to identify an alcohol?

    • C-H bond peak
    • C-O bond peak
    • O-H bond peak
    • C=O bond peak
  4. Which bond causes the IR absorption peak found at approximately 3000 cm⁻¹ in most organic compounds?

    • C-C bond
    • C=O bond
    • C-H bond
    • O-H bond
  5. What quantity does the mass-to-charge ratio of the molecular ion peak give?

    • Molar gas volume
    • Relative molecular mass
    • Empirical formula mass
    • Relative atomic mass
  6. A small M+1 peak in a mass spectrum of an organic compound is mainly caused by which isotope?

    • Hydrogen-2 (deuterium)
    • Carbon-13
    • Oxygen-18
    • Nitrogen-15
  7. Which gas in the atmosphere absorbs infrared radiation through its C-H bonds and contributes to global warming?

    • Argon, Ar
    • Methane, CH4
    • Nitrogen, N2
    • Oxygen, O2
  8. The molecular ion peak of a compound appears at m/z = 46. What is the relative molecular mass of the compound?

    • 47
    • 46
    • 92
    • 45
  9. A mass spectrum of an unknown organic compound shows a fragment at m/z = 15. Which ion is most likely responsible?

    • CO+
    • CH3+
    • C2H5+
    • COOH+
  10. A compound has 6 carbon atoms. Approximately what is the size of its M+1 peak relative to its M peak?

    • About 11 per cent
    • About 0.6 per cent
    • About 6.6 per cent
    • About 1.1 per cent
  11. A compound is found by elemental analysis to contain 40.0% C, 6.7% H and 53.3% O by mass. What is its empirical formula?

    • C2H4O2
    • C2H5O
    • CH2O
    • CHO
  12. An IR spectrum has absorptions at 2500–3300 cm⁻¹ and 1710 cm⁻¹. Which functional group is present?

    • Ester
    • Alcohol
    • Aldehyde
    • Carboxylic acid
  13. A compound with Mr 88 shows a strong IR absorption near 1740 cm^-1 but no broad O-H absorption. Which functional group is most likely present?

    • An ester
    • A primary alcohol
    • A carboxylic acid
    • An amine
  14. An IR spectrum of a compound shows only a broad absorption between 3200 and 3550 cm^-1 and no C=O absorption. Which type of compound is most likely?

    • An alcohol
    • An aldehyde
    • A carboxylic acid
    • A ketone
  15. Why can carbon monoxide and nitrogen monoxide pollutants in exhaust fumes be detected using IR spectroscopy?

    • Ions scatter radiation
    • Gases are coloured
    • Bonds absorb IR
    • Molecules emit IR
  16. A compound has a molecular ion peak at m/z = 58 and a strong IR absorption at about 1715 cm^-1 with no O-H absorption. Which compound fits best?

    • Propanone, CH3COCH3
    • Propan-1-ol, CH3CH2CH2OH
    • Propan-2-ol, CH3CH(OH)CH3
    • Propenoic acid, CH2=CHCOOH
  17. Which isotope causes the M+1 peak in an organic mass spectrum?

    • Carbon-14
    • Carbon-12
    • Carbon-13
    • Hydrogen-2
  18. What chemical formula is determined directly from elemental analysis percentage data?

    • Molecular formula
    • Displayed formula
    • Empirical formula
    • Structural formula
  19. Which wavenumber range is typical for the C=O absorption in an IR spectrum?

    • About 1680-1750 cm^-1
    • About 3200-3550 cm^-1
    • About 600-800 cm^-1
    • About 2100-2260 cm^-1
  20. A compound contains 85.7% carbon and 14.3% hydrogen by mass. What is its empirical formula?

    • C2H4
    • CH
    • CH2
    • C3H7

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