Lesson 3.1.5.5

3.1.5.5 Catalysts Quiz: AQA Chemistry, Unit 1

20 questions

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Lesson 3.1.5.5, Catalysts: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.

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The 20 questions

  1. What is the defining property of a catalyst in a chemical reaction?

    • It increases the equilibrium yield of product and is used up in the reaction
    • It increases the enthalpy change of the reaction and is converted into product
    • It increases the rate of a reaction and is chemically unchanged at the end of it
    • It lowers the rate of a reaction by stabilising the reactants in a fixed composition
  2. How does a catalyst increase the rate of a chemical reaction?

    • By increasing the activation energy of the forward reaction only
    • By raising the temperature of the reacting mixture above the set value
    • By providing an alternative reaction route with a lower activation energy
    • By increasing the enthalpy change of the reaction so more energy is released
  3. On a Maxwell-Boltzmann distribution, what does a catalyst change at a fixed temperature?

    • The position of the peak, moving it to a higher temperature on the graph
    • The total area under the curve, so more molecules exist in the mixture
    • The total number of molecules that have energy above zero
    • The activation energy, so a larger area under the curve lies beyond it
  4. Which statement about a catalyst and the enthalpy change of a reaction is correct?

    • A catalyst changes the enthalpy change only when the reaction is endothermic
    • A catalyst does not change the enthalpy change of the reaction
    • A catalyst makes the enthalpy change more exothermic by its own energy
    • A catalyst lowers the enthalpy change by the amount of activation energy saved
  5. A catalyst lowers the activation energy for a reaction. What does this do to the activation energies of the forward and reverse reactions?

    • It raises both activation energies by the same amount to keep the rate steady
    • It lowers both the forward and the reverse activation energies
    • It raises the reverse activation energy and lowers the forward one
    • It lowers only the forward activation energy and leaves the reverse unchanged
  6. At 300 K, the uncatalysed activation energy is 80 kJ/mol and the catalysed value is 50 kJ/mol. Using k = Ae^(-Ea/RT) with the same A and R = 8.314 J/(K mol), roughly how many times faster is the catalysed reaction?

    • About 1.7 x 10^5 times faster
    • About 1.7 x 10^2 times faster
    • About 3.0 x 10^1 times faster
    • About 1.2 x 10^1 times faster
  7. A reaction is carried out at a fixed temperature, and a catalyst is added. Which explanation for the faster rate, based on a Maxwell-Boltzmann distribution, is correct?

    • The curve becomes steeper, so the molecules travel faster and collide more often
    • The total area under the curve increases, meaning more molecules are present in the vessel
    • More molecules have energy at or above the lower activation energy, shown by a larger area beyond it
    • The peak of the distribution moves to higher energy, so molecules collide with more energy
  8. In the Haber process, solid iron is used as a catalyst. Which statement explains a practical advantage of a heterogeneous catalyst such as this?

    • The solid is consumed slowly so the product is contaminated with metal atoms each cycle
    • The solid dissolves the gases so that they react throughout the whole of the liquid phase
    • The solid raises the temperature of the gases so that the equilibrium yield increases
    • The reaction takes place on its surface and the solid catalyst can be separated from the gas mixture
  9. A catalyst is added to the reaction A + B to give C. After the reaction finishes, how much catalyst is left compared with the start?

    • The same amount as at the start, because it is regenerated in the reaction cycle
    • More than the original amount, because the catalyst is itself a product of the reaction
    • None, because all of the catalyst is consumed in forming the product molecules
    • Half of the original amount, because half of it has been used up in the reaction
  10. Which feature of an energy profile diagram shows that a reaction has been catalysed?

    • A lower peak, showing a lower activation energy between the same reactant and product energy levels
    • Reactant and product energy levels that are different from the uncatalysed reaction
    • A peak of the same height but moved to the right, showing a longer reaction time
    • A higher peak, showing that more energy is needed to start the reaction
  11. At 298 K, reducing the activation energy from 60 to 40 kJ/mol with A unchanged raises the rate by a factor of about how much? Use RT = 2478 J/mol.

    • About 3.2 x 10^3
    • About 1.5 x 10^2
    • About 3.2 x 10^1
    • About 6.0 x 10^4
  12. Which equation describes how the rate constant k depends on temperature and activation energy, and what the catalyst changes in it?

    • k = A/(RT): a catalyst lowers the temperature, which increases the value of k
    • k = Ae^(Ea/RT): a catalyst raises Ea, so k increases as the temperature falls
    • k = Ae^(-Ea/RT): a catalyst lowers Ea, so the exponential term and k increase
    • k = Ea/(RT): a catalyst increases the Arrhenius constant A, which raises k
  13. A reaction has Ea = 100 kJ/mol. A catalyst lowers it to 75 kJ/mol at the same temperature. Which expression gives the ratio of the catalysed rate constant to the uncatalysed rate constant?

    • exp(100000/(RT)) minus exp(75000/(RT))
    • exp(25000/(RT))
    • 25000/(RT)
    • exp(-25000/(RT))
  14. Platinum in a catalytic converter converts carbon monoxide to carbon dioxide. Why is the metal surface important to its action?

    • Gas molecules adsorb onto its large surface area, which weakens bonds and lowers the activation energy
    • The gases dissolve into the metal so that no gas remains in the exhaust after treatment
    • The metal heats the gas molecules to high speeds, so they collide more often on the surface
    • Platinum forms a stable bond with carbon dioxide, which removes the product from the mixture
  15. Which change would not increase the rate of a reaction, as explained by collision theory and the Maxwell-Boltzmann distribution?

    • Increasing the concentration of the gaseous reactants in a closed vessel
    • Increasing the surface area of a solid catalyst that is exposed to the reactants
    • Raising the temperature of the reacting mixture at the same pressure
    • Using a catalyst whose alternative route has a higher activation energy than the uncatalysed route
  16. At 400 K, lowering the activation energy from 90 to 60 kJ/mol with A unchanged increases the rate by about what factor? Use RT = 3326 J/mol.

    • About 3.0 x 10^2
    • About 8.3 x 10^3
    • About 2.0 x 10^5
    • About 8.3 x 10^1
  17. Two catalysts act on the same reaction at 300 K. Catalyst X lowers the activation energy by 10 kJ/mol more than catalyst Y. Assuming the rate ratio depends only on exp(10000/RT) with RT = 2494 J/mol, roughly how much faster is X?

    • About 4 times faster
    • About 2500 times faster
    • About 10 times faster
    • About 55 times faster
  18. At 300 K, what fraction of molecules has energy at least equal to an activation energy of 50 kJ/mol, using exp(-Ea/RT) with R = 8.314 J/(K mol)?

    • About 2.0 x 10^-4
    • About 2.0 x 10^-9
    • About 1.0 x 10^-20
    • About 5.0 x 10^-1
  19. Which statement about enzymes, which are biological catalysts, is correct?

    • Enzymes are used up in every reaction and must be continually replaced in the cell
    • Enzymes work best at very high temperatures, above 100 C, in all living cells
    • Enzymes are usually highly specific, acting on one substrate or a closely related type of reaction
    • Enzymes change the enthalpy change of the reactions they catalyse in the cell
  20. A company says a catalyst lets it run an exothermic reversible reaction at a lower temperature, avoiding the energy cost of heating. What is the main trade-off to evaluate?

    • A lower temperature always gives a higher rate, so the catalyst is unnecessary in every case
    • The catalyst is consumed quickly, so the company must reheat the reactor to restore its activity
    • A lower temperature may keep yield high for an exothermic reaction, but the rate must still be acceptable
    • A catalyst raises the equilibrium yield of an exothermic reaction, so temperature is irrelevant

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