Lesson 3.1.5.5
3.1.5.5 Catalysts Quiz: AQA Chemistry, Unit 1
20 questions
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Lesson 3.1.5.5, Catalysts: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.
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The 20 questions
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What is the defining property of a catalyst in a chemical reaction?
- It increases the equilibrium yield of product and is used up in the reaction
- It increases the enthalpy change of the reaction and is converted into product
- It increases the rate of a reaction and is chemically unchanged at the end of it
- It lowers the rate of a reaction by stabilising the reactants in a fixed composition
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How does a catalyst increase the rate of a chemical reaction?
- By increasing the activation energy of the forward reaction only
- By raising the temperature of the reacting mixture above the set value
- By providing an alternative reaction route with a lower activation energy
- By increasing the enthalpy change of the reaction so more energy is released
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On a Maxwell-Boltzmann distribution, what does a catalyst change at a fixed temperature?
- The position of the peak, moving it to a higher temperature on the graph
- The total area under the curve, so more molecules exist in the mixture
- The total number of molecules that have energy above zero
- The activation energy, so a larger area under the curve lies beyond it
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Which statement about a catalyst and the enthalpy change of a reaction is correct?
- A catalyst changes the enthalpy change only when the reaction is endothermic
- A catalyst does not change the enthalpy change of the reaction
- A catalyst makes the enthalpy change more exothermic by its own energy
- A catalyst lowers the enthalpy change by the amount of activation energy saved
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A catalyst lowers the activation energy for a reaction. What does this do to the activation energies of the forward and reverse reactions?
- It raises both activation energies by the same amount to keep the rate steady
- It lowers both the forward and the reverse activation energies
- It raises the reverse activation energy and lowers the forward one
- It lowers only the forward activation energy and leaves the reverse unchanged
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At 300 K, the uncatalysed activation energy is 80 kJ/mol and the catalysed value is 50 kJ/mol. Using k = Ae^(-Ea/RT) with the same A and R = 8.314 J/(K mol), roughly how many times faster is the catalysed reaction?
- About 1.7 x 10^5 times faster
- About 1.7 x 10^2 times faster
- About 3.0 x 10^1 times faster
- About 1.2 x 10^1 times faster
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A reaction is carried out at a fixed temperature, and a catalyst is added. Which explanation for the faster rate, based on a Maxwell-Boltzmann distribution, is correct?
- The curve becomes steeper, so the molecules travel faster and collide more often
- The total area under the curve increases, meaning more molecules are present in the vessel
- More molecules have energy at or above the lower activation energy, shown by a larger area beyond it
- The peak of the distribution moves to higher energy, so molecules collide with more energy
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In the Haber process, solid iron is used as a catalyst. Which statement explains a practical advantage of a heterogeneous catalyst such as this?
- The solid is consumed slowly so the product is contaminated with metal atoms each cycle
- The solid dissolves the gases so that they react throughout the whole of the liquid phase
- The solid raises the temperature of the gases so that the equilibrium yield increases
- The reaction takes place on its surface and the solid catalyst can be separated from the gas mixture
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A catalyst is added to the reaction A + B to give C. After the reaction finishes, how much catalyst is left compared with the start?
- The same amount as at the start, because it is regenerated in the reaction cycle
- More than the original amount, because the catalyst is itself a product of the reaction
- None, because all of the catalyst is consumed in forming the product molecules
- Half of the original amount, because half of it has been used up in the reaction
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Which feature of an energy profile diagram shows that a reaction has been catalysed?
- A lower peak, showing a lower activation energy between the same reactant and product energy levels
- Reactant and product energy levels that are different from the uncatalysed reaction
- A peak of the same height but moved to the right, showing a longer reaction time
- A higher peak, showing that more energy is needed to start the reaction
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At 298 K, reducing the activation energy from 60 to 40 kJ/mol with A unchanged raises the rate by a factor of about how much? Use RT = 2478 J/mol.
- About 3.2 x 10^3
- About 1.5 x 10^2
- About 3.2 x 10^1
- About 6.0 x 10^4
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Which equation describes how the rate constant k depends on temperature and activation energy, and what the catalyst changes in it?
- k = A/(RT): a catalyst lowers the temperature, which increases the value of k
- k = Ae^(Ea/RT): a catalyst raises Ea, so k increases as the temperature falls
- k = Ae^(-Ea/RT): a catalyst lowers Ea, so the exponential term and k increase
- k = Ea/(RT): a catalyst increases the Arrhenius constant A, which raises k
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A reaction has Ea = 100 kJ/mol. A catalyst lowers it to 75 kJ/mol at the same temperature. Which expression gives the ratio of the catalysed rate constant to the uncatalysed rate constant?
- exp(100000/(RT)) minus exp(75000/(RT))
- exp(25000/(RT))
- 25000/(RT)
- exp(-25000/(RT))
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Platinum in a catalytic converter converts carbon monoxide to carbon dioxide. Why is the metal surface important to its action?
- Gas molecules adsorb onto its large surface area, which weakens bonds and lowers the activation energy
- The gases dissolve into the metal so that no gas remains in the exhaust after treatment
- The metal heats the gas molecules to high speeds, so they collide more often on the surface
- Platinum forms a stable bond with carbon dioxide, which removes the product from the mixture
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Which change would not increase the rate of a reaction, as explained by collision theory and the Maxwell-Boltzmann distribution?
- Increasing the concentration of the gaseous reactants in a closed vessel
- Increasing the surface area of a solid catalyst that is exposed to the reactants
- Raising the temperature of the reacting mixture at the same pressure
- Using a catalyst whose alternative route has a higher activation energy than the uncatalysed route
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At 400 K, lowering the activation energy from 90 to 60 kJ/mol with A unchanged increases the rate by about what factor? Use RT = 3326 J/mol.
- About 3.0 x 10^2
- About 8.3 x 10^3
- About 2.0 x 10^5
- About 8.3 x 10^1
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Two catalysts act on the same reaction at 300 K. Catalyst X lowers the activation energy by 10 kJ/mol more than catalyst Y. Assuming the rate ratio depends only on exp(10000/RT) with RT = 2494 J/mol, roughly how much faster is X?
- About 4 times faster
- About 2500 times faster
- About 10 times faster
- About 55 times faster
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At 300 K, what fraction of molecules has energy at least equal to an activation energy of 50 kJ/mol, using exp(-Ea/RT) with R = 8.314 J/(K mol)?
- About 2.0 x 10^-4
- About 2.0 x 10^-9
- About 1.0 x 10^-20
- About 5.0 x 10^-1
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Which statement about enzymes, which are biological catalysts, is correct?
- Enzymes are used up in every reaction and must be continually replaced in the cell
- Enzymes work best at very high temperatures, above 100 C, in all living cells
- Enzymes are usually highly specific, acting on one substrate or a closely related type of reaction
- Enzymes change the enthalpy change of the reactions they catalyse in the cell
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A company says a catalyst lets it run an exothermic reversible reaction at a lower temperature, avoiding the energy cost of heating. What is the main trade-off to evaluate?
- A lower temperature always gives a higher rate, so the catalyst is unnecessary in every case
- The catalyst is consumed quickly, so the company must reheat the reactor to restore its activity
- A lower temperature may keep yield high for an exothermic reaction, but the rate must still be acceptable
- A catalyst raises the equilibrium yield of an exothermic reaction, so temperature is irrelevant
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