Lesson 6.2.5
6.2.5 Organic synthesis Quiz: OCR Chemistry, Unit 5
20 questions
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Lesson 6.2.5, Organic synthesis: 20 multiple choice questions for the OCR Chemistry (H432), Unit 5: Organic chemistry and analysis, written with Revision Ninja.
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The 20 questions
-
Which piece of apparatus is fitted vertically above the flask when heating under reflux?
- Liebig condenser
- Buchner funnel
- Separating funnel
- Fractionating column
-
What is the main purpose of heating an organic reaction mixture under reflux?
- Prevent reagent loss
- Increase product yield
- Speed up filtration
- Remove solvent completely
-
Which technique is used to rapidly separate solid crystals from a liquid under reduced pressure?
- Buchner filtration
- Gravity filtration
- Fractional distillation
- Simple distillation
-
In recrystallisation, how should the impure solid initially be dissolved?
- Minimum cold solvent
- Minimum hot solvent
- Excess hot solvent
- Excess cold solvent
-
Why do small quantities of soluble impurities remain in solution during cooling in recrystallisation?
- High melting point
- Low concentration
- Insoluble nature
- High density
-
How does the melting point of an impure solid compare to a pure sample?
- Higher and broader
- Lower and broader
- Higher and sharper
- Lower and sharper
-
A synthesized solid melts over 128–130 °C, but the pure literature value is 132 °C. Why?
- Product fully decomposed
- Product absorbed solvent
- Product lost carbon
- Product contains impurities
-
Which acid catalyst is mixed with concentrated nitric acid to nitrate benzene?
- Concentrated sulfuric acid
- Concentrated hydrochloric acid
- Concentrated ethanoic acid
- Dilute sulfuric acid
-
Which reagents convert nitrobenzene into phenylamine in a two-stage reduction?
- LiAlH4 and ether
- Tin and HCl
- NaBH4 and ethanol
- Hydrogen and nickel
-
Which compound reacts with ethanoic acid in the presence of acid to form ethyl ethanoate?
- Ethane
- Chloroethane
- Ethanol
- Ethanal
-
Which reagents convert propanoic acid into N-methylpropanamide in a two-step synthesis?
- NaOH then CH3NH2
- NaBH4 then CH3NH2
- SOCl2 then CH3NH2
- SOCl2 then NH3
-
Which sequence of reagents converts bromomethane into ethylamine in two steps?
- NH3 then H2/Ni
- KCN then H2/Ni
- KCN then NaBH4
- HNO3 then H2/Ni
-
Which molecule contains both an amine and a carboxylic acid group?
- An amino acid
- An ester
- An acyl chloride
- A nitrile
-
Which functional group identification is correct for a molecule with an -OH group on an aromatic ring?
- An amide group
- An ester group
- A carboxylic acid group
- A phenol group
-
Ethanol and ethanoic acid (0.20 mol each) are converted into ethyl ethanoate, Mr 88, in a 60 per cent yield. What is the actual mass of ester obtained?
- 10.6 g
- 8.8 g
- 17.6 g
- 5.3 g
-
A student makes 0.12 mol of ethyl ethanoate from a route with a 60 per cent overall yield. What was the theoretical number of moles?
- 0.12 mol
- 0.30 mol
- 0.20 mol
- 0.072 mol
-
What property is assessed by comparing a solid product's melting point to literature values?
- Molar mass
- Solubility
- Purity
- Yield
-
Which technique is required to oxidise propan-1-ol fully to propanoic acid using acidified dichromate?
- Distillation
- Cold room temperature
- Heating under reflux
- Reflux with NaBH4
-
Which reaction forms a new carbon–carbon bond in organic synthesis?
- Nitration of benzene
- Ester hydrolysis
- Friedel–Crafts alkylation
- Reduction of aldehydes
-
Why is an aldehyde distilled off immediately during the oxidation of a primary alcohol?
- To increase yield
- To prevent reduction
- To neutralise acid
- To prevent oxidation
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