Lesson 6.2.4

6.2.4 Carbon–carbon bond formation Quiz: OCR Chemistry, Unit 5

20 questions

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Lesson 6.2.4, Carbon–carbon bond formation: 20 multiple choice questions for the OCR Chemistry (H432), Unit 5: Organic chemistry and analysis, written with Revision Ninja.

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The 20 questions

  1. Which species acts as the nucleophile when a haloalkane reacts with ethanolic potassium cyanide?

    • Ethanol molecule
    • Halide ion
    • Potassium ion
    • Cyanide ion
  2. What is the product of bromoethane reacting with potassium cyanide in ethanol?

    • Propanenitrile, CH3CH2CN
    • Ethylamine, CH3CH2NH2
    • Propan-1-ol, CH3CH2CH2OH
    • Ethanenitrile, CH3CN
  3. What type of mechanism does the reaction of a haloalkane with CN- follow?

    • Free radical substitution
    • Nucleophilic substitution
    • Electrophilic addition
    • Electrophilic substitution
  4. Propanenitrile is reduced by H2 over a nickel catalyst. What is the product?

    • Propan-2-amine, CH3CH(NH2)CH3
    • Propanoic acid, CH3CH2COOH
    • Propylamine, CH3CH2CH2NH2
    • Propan-1-ol, CH3CH2CH2OH
  5. Propanenitrile is hydrolysed by heating with dilute acid. What is the product?

    • Propanamide only
    • Propanoic acid
    • Propan-1-ol
    • Propylamine
  6. Which reaction attaches an alkyl group to a benzene ring using a haloalkane and catalyst?

    • Nitration
    • Friedel–Crafts alkylation
    • Halogenation
    • Friedel–Crafts acylation
  7. What is the organic product when chloromethane reacts with benzene in the presence of aluminium chloride?

    • Phenylmethanol
    • Benzoic acid
    • Methylbenzene
    • Chlorobenzene only
  8. Why must Friedel–Crafts reactions be conducted under anhydrous conditions?

    • Water hydrolyses benzene
    • Water evaporates rapidly
    • Water oxidises haloalkane
    • Water deactivates catalyst
  9. Which mechanism describes the reaction between a haloalkane and potassium cyanide?

    • Electrophilic addition
    • Electrophilic substitution
    • Nucleophilic substitution
    • Nucleophilic addition
  10. What is the product of ethanal reacting with HCN followed by acid hydrolysis of the nitrile?

    • Ethanoic acid
    • 2-hydroxypropanoic acid
    • Propanoic acid
    • 2-hydroxypropanal
  11. What type of organic compound is formed by the reduction of a nitrile with hydrogen gas?

    • Carboxylic acid
    • Amide
    • Secondary amine
    • Primary amine
  12. A chemist prepares ethanoic acid with two steps: CH3Cl + CN-, then acid hydrolysis. How many carbon atoms are in the final product?

    • Three
    • Two
    • One
    • Four
  13. Which organic reagent reacts with benzene in the presence of AlCl3 to form an aromatic ketone?

    • Alkyl chloride
    • Haloalkane
    • Carboxylic acid
    • Acyl chloride
  14. Which ion reacts with a haloalkane to increase its carbon chain length by one carbon?

    • Hydroxide ion
    • Hydride ion
    • Cyanide ion
    • Nitrate ion
  15. How many carbon atoms are in the nitrile formed when 1-bromobutane reacts with KCN in ethanol?

    • Five
    • Six
    • Four
    • Three
  16. What is the product of 2-bromopropane reacting with KCN in ethanol?

    • 2-methylpropanenitrile, (CH3)2CHCN
    • Butanenitrile, CH3CH2CH2CN
    • 2-methylpropan-2-ol
    • Propan-2-amine
  17. What is the molecular formula of propanenitrile?

    • C3H6O
    • C3H7N
    • C2H5N
    • C3H5N
  18. What is the functional group present in propanenitrile?

    • Amine
    • Nitrile
    • Amide
    • Nitro
  19. What is the role of aluminium chloride in Friedel–Crafts alkylation of benzene?

    • Oxidising agent
    • Reducing agent
    • Nucleophilic catalyst
    • Halogen carrier catalyst
  20. What organic product forms when benzene reacts with 2-bromopropane in the presence of AlCl3?

    • Propylbenzene
    • Bromobenzene
    • (1-methylethyl)benzene
    • Phenylethanone

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