Lesson 3.3.5.2
3.3.5.2 Oxidation of alcohols Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.5.2, Oxidation of alcohols: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
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What is the product formed when a primary alcohol is oxidised with distillation of the product?
- An alkene
- A ketone
- An aldehyde
- A carboxylic acid
-
What is the product of heating a primary alcohol under reflux with excess oxidising agent?
- A carboxylic acid
- A ketone
- An aldehyde
- An ester only
-
What is the product of oxidising a secondary alcohol?
- An alkene
- A carboxylic acid
- A ketone
- An aldehyde
-
Why are tertiary alcohols not easily oxidised?
- They contain a C=C double bond
- They have no hydrogen on the carbon bearing the OH group
- They have too many hydrogens to be oxidised
- They are ionic in structure
-
Which oxidising agent is used for the oxidation of alcohols in this specification?
- Ethanol
- Dilute sodium hydroxide
- Acidified potassium dichromate(VI)
- Sodium chloride solution
-
What is the colour change of acidified potassium dichromate(VI) during oxidation of an alcohol?
- Colourless to blue
- Purple to colourless
- Green to orange
- Orange to green
-
Write the equation for the oxidation of ethanol to ethanal using [O] as the oxidant.
- CH3CH2OH + [O] -> CH3CH3 + O2
- CH3CH2OH + 2[O] -> CH2=CH2 + 2H2O
- CH3CH2OH + [O] -> CH3CHO + H2O
- CH3CH2OH + [O] -> CH3COOH + H2O
-
What is the product when ethanol is oxidised fully to a carboxylic acid?
- Ethene
- Propanone
- Ethanal
- Ethanoic acid
-
Which compound is formed by oxidation of propan-2-ol?
- Propanoic acid
- Propanal
- Propanone
- Propan-1-ol
-
Which chemical test distinguishes aldehydes from ketones?
- Lime water
- Sodium carbonate
- Bromine water
- Tollens' reagent or Fehling's solution
-
What is observed when an aldehyde is warmed with Tollens' reagent?
- A silver mirror forms on the inside of the tube
- A purple colour forms
- A green precipitate forms
- Nothing happens
-
What is observed when an aldehyde is warmed with Fehling's solution?
- A red precipitate of copper(I) oxide forms
- A colourless solution forms
- A white precipitate forms
- A blue solution remains unchanged
-
What is the result of adding Tollens' reagent to a ketone?
- A red precipitate forms
- A green solution forms
- A silver mirror forms
- No reaction occurs
-
Why does the method of oxidising a primary alcohol determine whether an aldehyde or carboxylic acid is obtained?
- Distilling off the aldehyde as it forms prevents its further oxidation, while reflux allows full oxidation
- Only heating without oxidant gives an acid
- The oxidising agent changes the alcohol to an alkene
- Reflux removes the aldehyde while distillation oxidises it fully
-
What is the product of the oxidation of butan-1-ol using reflux with excess dichromate?
- Butan-2-one
- But-1-ene
- Butanoic acid
- Butanal
-
Which of these compounds gives a positive result with Tollens' reagent?
- Propanone
- Propan-2-ol
- Propanal
- Butane
-
Which product is formed from the oxidation of 2-methylpropan-2-ol?
- 2-methylpropanal
- 2-methylpropanoic acid
- No oxidation occurs under normal conditions
- 2-methylpropanone
-
Explain why the oxidation of an alcohol with [O] gives water as a by-product.
- Two hydrogens are removed from the alcohol and combine with the oxygen from the oxidant to form water
- The oxidant contains hydrogen that forms water
- Water is a product of the alkene only
- Water is formed by ionic recombination of the alcohol
-
Explain why a student can use a chemical test to show that an unknown compound is an aldehyde rather than a ketone.
- Ketones are always oxidised more easily than aldehydes
- Aldehydes contain a C-OH group that is inert to all reagents
- Both aldehydes and ketones react equally with silver ions
- Aldehydes contain a C=O at the end of the chain and are oxidised by Tollens' reagent, unlike ketones
-
Explain why the alcohol oxidation to a ketone cannot continue to a carboxylic acid.
- A ketone has a hydroxide group that blocks oxidation
- A ketone is an alkene that resists oxidation
- A ketone is ionic and does not react with oxidants
- A ketone has no hydrogen attached to its carbonyl carbon, so it cannot be oxidised further without breaking the chain
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