Lesson 3.3.5.3
3.3.5.3 Alcohols: Elimination Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.5.3, Alcohols: Elimination: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
-
What type of reaction forms an alkene from an alcohol?
- Addition
- Free-radical substitution
- Elimination (dehydration)
- Oxidation
-
What catalyst is used to dehydrate an alcohol to an alkene?
- Potassium manganate(VII) only
- Concentrated acid such as sulfuric or phosphoric acid
- Nickel
- Ultraviolet light
-
What is the product of heating cyclohexanol with an acid catalyst?
- Cyclohexanoic acid
- Cyclohexene
- Cyclohexane only
- Cyclohexanone
-
Which of the following is the first step in the acid-catalysed elimination of water from an alcohol?
- Removal of a hydrogen from the alkene
- Protonation of the OH group
- Formation of a radical from water
- Addition of Br2 across the C-O bond
-
In the mechanism of acid-catalysed alcohol elimination, what is the intermediate formed after water leaves?
- A carbanion
- A carbocation
- A free radical only
- An ester
-
Which compound is formed when ethanol is dehydrated with concentrated sulfuric acid at high temperature?
- Ethanal
- Ethanoic acid
- Ethene
- Ethane
-
Why are alkenes made from alcohols useful?
- They contain no C=C bond
- They are ionic salts
- They can be used to make addition polymers without using monomers from crude oil
- They are always used as fuels only
-
Which alcohol is most suitable for making cyclohexene in the required practical?
- Cyclohexane
- Cyclohexanol
- Cyclohexanone
- Cyclohexanoic acid
-
How is cyclohexene purified in the required practical after dehydration?
- By adding excess bromine
- By electrolysis
- Using a separating funnel and then distillation
- By filtration through paper only
-
What is the molecular formula of the alkene formed by dehydrating butan-2-ol?
- C4H10O
- C4H6
- C4H8
- C4H10
-
What is the balanced equation for the dehydration of ethanol to ethene?
- C2H5OH -> C2H4O + H2
- 2C2H5OH -> C2H4 + 2H2O
- C2H5OH -> C2H4 + H2O
- C2H5OH -> C2H6 + O
-
Which product is formed from the elimination of water from propan-2-ol?
- Propanal
- Propan-1-ol
- Propanone
- Propene
-
Why is elimination from a secondary alcohol typically drawn with the more substituted alkene as the major product?
- Water must be retained in the product
- Radicals form the major product
- The more substituted alkene is more stable
- The less substituted alkene is always more stable
-
Which reagent is used in the dehydration of cyclohexanol in the laboratory practical?
- Bromine water
- Sodium hydroxide
- Silver nitrate
- Concentrated phosphoric acid
-
What is the role of the acid in the dehydration of an alcohol?
- It protonates the OH group so water is a better leaving group
- It removes the carbon chain
- It oxidises the alcohol to a ketone
- It removes all the hydrogen atoms
-
Which species is removed as a by-product when an alcohol is dehydrated?
- Carbon dioxide
- Sodium chloride
- Water
- Hydrogen gas
-
Why are the alkenes formed by elimination reactions of alcohols useful for addition polymer production?
- They have C=C bonds that can open to form addition polymers
- They are always ionic
- They are always aromatic rings
- They contain no double bonds
-
Explain why an acid catalyst is needed for alcohol elimination rather than heating alone.
- The acid removes hydrogen from the alkene to make it stable
- The acid protonates the OH group, making water a better leaving group so elimination proceeds more readily
- Acid prevents the formation of any carbocation
- Heating alone always gives an ester, so acid is needed
-
Explain why the dehydration of an alcohol and the hydration of an alkene are reverse reactions in principle.
- Both involve the same C-O and C=C bonds in an equilibrium-type relationship between alkene plus water and alcohol
- Hydration forms an alkene and dehydration forms an alcohol and salt
- Both reactions produce only ionic compounds
- Both reactions are free-radical with no catalyst
-
Which alcohol gives only one possible alkene on dehydration?
- Propan-2-ol but with two alkenes
- Butan-2-ol
- Pentan-2-ol
- Ethanol
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