Lesson 3.2.5.5

3.2.5.5 Variable oxidation states Quiz: AQA Chemistry, Unit 2

20 questions

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Lesson 3.2.5.5, Variable oxidation states: 20 multiple choice questions for the AQA Chemistry (7405), Unit 2: Inorganic chemistry, written with Revision Ninja.

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The 20 questions

  1. What is the common oxidation state of vanadium in the vanadate(V) ion?

    • +5
    • +3
    • +2
    • +4
  2. What is the reducing agent used to reduce vanadate(V) ions in acidic solution in the AQA practical?

    • Zinc
    • Potassium iodide
    • Sodium hydroxide
    • Chlorine
  3. Which oxidation states of vanadium are formed when vanadate(V) is reduced by zinc in acidic solution?

    • +5 only
    • 0 and +1
    • +4, +3 and +2
    • +6 and +7
  4. Which reagent is used to distinguish aldehydes from ketones by a silver mirror?

    • Tollens' reagent
    • Dilute sodium hydroxide
    • Aqueous sodium chloride
    • Acidified potassium manganate(VII)
  5. Which species is reduced to metallic silver in the test with Tollens' reagent?

    • Cu2+
    • NH3
    • OH-
    • [Ag(NH3)2]+
  6. In the reaction of Fe2+ with MnO4- in acid, what is the change in oxidation state of manganese?

    • +7 to +2
    • +7 to +6
    • +7 to +4
    • +2 to +7
  7. What is the balanced equation for Fe2+ reacting with MnO4- in acid solution?

    • Fe2+ + MnO4- -> Fe3+ + MnO2
    • Fe2+ + 2MnO4- -> Fe3+ + 2Mn2+ + O2
    • 5Fe2+ + MnO4- + 4H+ -> 5Fe3+ + Mn2+ + 2H2O
    • 5Fe2+ + MnO4- + 8H+ -> 5Fe3+ + Mn2+ + 4H2O
  8. What is the balanced equation for ethanedioate reacting with manganate(VII) in acid?

    • 2C2O4^2- + MnO4- + 8H+ -> 4CO2 + Mn2+ + 4H2O
    • 5C2O4^2- + 2MnO4- + 16H+ -> 10CO2 + 2Mn2+ + 8H2O
    • C2O4^2- + MnO4- -> CO2 + Mn2+
    • 5C2O4^2- + 2MnO4- + 8H+ -> 10CO2 + 2Mn2+ + 4H2O
  9. A 25.0 cm3 sample of Fe2+ solution is titrated with 0.0200 mol dm-3 KMnO4, using 20.0 cm3 at the endpoint. How many moles of MnO4- are used?

    • 4.00 x 10^-4 mol
    • 2.00 x 10^-3 mol
    • 1.00 x 10^-3 mol
    • 5.00 x 10^-4 mol
  10. Using the answer to the previous question, how many moles of Fe2+ are in the sample titrated with 4.00 x 10^-4 mol of MnO4-?

    • 1.00 x 10^-2 mol
    • 8.00 x 10^-4 mol
    • 4.00 x 10^-4 mol
    • 2.00 x 10^-3 mol
  11. In a titration of ethanedioate with acidified KMnO4, 20.0 cm3 of 0.0200 mol dm-3 KMnO4 is used. How many moles of ethanedioate, C2O4^2-, react?

    • 4.00 x 10^-4 mol
    • 5.00 x 10^-4 mol
    • 2.00 x 10^-3 mol
    • 1.00 x 10^-3 mol
  12. What is the oxidation state of vanadium in the VO2+ ion?

    • +3
    • +2
    • +4
    • +5
  13. Why is no separate indicator needed in a titration of Fe2+ with acidified KMnO4?

    • MnO4- is purple and is reduced to colourless Mn2+, so the endpoint is seen from the first excess of purple colour
    • Iron(II) changes colour to show the endpoint
    • MnO4- is colourless and Fe2+ is purple
    • The reaction produces a precipitate that marks the endpoint
  14. Which factor influences the redox potential for a transition metal ion changing to a lower oxidation state?

    • pH and the ligand present
    • Only the volume of the titration flask
    • Only the colour of the solution
    • Only the temperature of the room
  15. Which change is a reduction in a redox titration?

    • Mn in MnO4- going from +7 to +2
    • Fe2+ going to Fe3+
    • C in C2O4^2- going to CO2
    • Hydrogen in H2O going to H+
  16. Which statement about the redox titration of hydrogen peroxide with manganate(VII) is correct?

    • H2O2 is always reduced to oxygen gas without any change
    • The method only measures the mass of sodium chloride
    • The method can find the concentration of H2O2 in hair bleach
    • Manganate(VII) is reduced by H2O2 to MnO2 only
  17. Which quantity can be found by a redox titration of iron(II) with manganate(VII)?

    • The density of iron metal
    • The mass of iron in an iron tablet
    • The melting point of iron
    • The boiling point of the solution
  18. Why does the reduction of vanadate(V) by zinc in acid produce a sequence of different colours?

    • Vanadium is colourless in every oxidation state
    • The acid changes the colour of vanadium metal only
    • Zinc reacts to form a different coloured oxide at each step
    • Each lower oxidation state of vanadium absorbs a different wavelength of visible light, so the colour changes
  19. Explain why the redox potential of the Fe3+/Fe2+ couple changes when the ligand is changed.

    • The ligand removes all electrons from the iron ion
    • The ligand is oxidised instead of the iron ion
    • The ligand stabilises one oxidation state more strongly, which shifts the electrode potential
    • The ligand has no effect on electrode potentials
  20. Which equation shows that Cu2+ is reduced in a reaction with iodide?

    • Cu2+ + Zn -> Zn2+ + Cu only
    • I- -> I2 + e-
    • 2Cu2+ + 4I- -> 2CuI + I2
    • Cu2+ + 2e- -> Cu+ + 2e-

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