Lesson 3.2.1.2
3.2.1.2 Physical properties of Period 3 elements Quiz: AQA Chemistry, Unit 2
20 questions
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Lesson 3.2.1.2, Physical properties of Period 3 elements: 20 multiple choice questions for the AQA Chemistry (7405), Unit 2: Inorganic chemistry, written with Revision Ninja.
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The 20 questions
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How does atomic radius change across Period 3 from sodium to chlorine?
- It stays the same, because all Period 3 elements have the same number of shells
- It decreases, because nuclear charge increases while the electrons stay in the same shell
- It increases then decreases, because the shielding changes sharply at silicon
- It increases, because each added electron moves into a new, larger shell
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Why does atomic radius decrease across Period 3?
- The number of shells increases, so the atoms become smaller in size as more protons are added to them
- The electrons are removed from the atoms, so the atoms shrink as the period goes on and more charge builds up
- The number of neutrons increases, so the nucleus repels the outer electrons more strongly across the period
- Nuclear charge increases while shielding stays similar, so the outer electrons are pulled closer to the nucleus
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Which Period 3 element has the largest atomic radius?
- Sodium
- Aluminium
- Chlorine
- Magnesium
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What is the general trend in first ionisation energy across Period 3 from Na to Ar?
- It increases steadily with no exceptions from sodium to argon
- It generally increases, with dips at aluminium and sulfur
- It is the same for all Period 3 elements
- It decreases steadily from sodium to argon
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Why is the first ionisation energy of magnesium higher than that of sodium?
- Sodium has more shielding from neutrons, so its outer electron is removed more easily
- Sodium has a higher nuclear charge, so its outer electron is held more strongly than in magnesium
- Magnesium has a greater nuclear charge and its outer electrons are in the same shell, so they are held more strongly
- Magnesium has an extra shell, so its outer electrons are further from the nucleus
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The first ionisation energy falls from magnesium to aluminium. Which explanation is correct?
- Aluminium has fewer protons than magnesium, so its outer electron is held more weakly by the nucleus overall
- Aluminium has more shielding from neutrons, which reduces its outer electron attraction to the nucleus strongly
- Aluminium has an extra shell, so its outer electron is much further from the nucleus than the magnesium electron
- The outer electron of aluminium is in a 3p subshell, which is higher in energy than 3s and slightly further from the nucleus
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The first ionisation energy falls from phosphorus to sulfur. Which explanation is correct?
- Sulfur has a paired electron in one 3p orbital, and the repulsion between the paired electrons makes one easier to remove
- Sulfur has no outer electrons in a 3p subshell, so its first ionisation energy is lower than that of phosphorus
- Sulfur has an extra shell, so its outer electrons are further from the nucleus and are held less tightly overall
- Sulfur has fewer protons than phosphorus, so its outer electrons are held more weakly by the nucleus overall
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Which element in Period 3 has the highest melting point, and why?
- Argon, because it has the largest atomic radius in the period, so its atoms are held together more strongly
- Sodium, because it has the most delocalised electrons per atom in the period
- Silicon, because it has a giant covalent structure with many strong covalent bonds
- Phosphorus, because it has the most strong intermolecular forces between its molecules in the solid form
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Why does magnesium have a higher melting point than sodium?
- Magnesium has a larger atomic radius, so its metallic bonds are longer and weaker and it melts at a lower point
- Magnesium forms covalent molecules, which need more energy to melt than metallic bonds, so it melts at a higher point
- Magnesium has fewer delocalised electrons than sodium, so its metallic bonding is weaker and it melts more easily
- Magnesium has two delocalised electrons per atom and a higher positive charge on its ions, so its metallic bonding is stronger
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Why do phosphorus, sulfur, chlorine and argon have low melting points compared with silicon?
- They are ionic compounds with low lattice enthalpies, so the ions separate easily when the solid is heated gently
- They have giant covalent structures in which the bonds are very weak, so they melt at low temperatures in every case
- They are simple molecular or atomic substances held together by weak London forces between molecules or atoms
- They are metals with few delocalised electrons, so their metallic bonds are weak and they melt easily at room temperature
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Which Period 3 element has the lowest melting point?
- Argon, which is monatomic with only weak London forces between atoms
- Silicon, which has the simplest structure of all the elements in the period
- Sodium, which has the fewest delocalised electrons per atom in the period
- Chlorine, which has the smallest molecules in the period, held together by weak forces
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Why is the first ionisation energy of argon higher than that of chlorine?
- Argon has no electrons in its outer shell, so it cannot lose an electron at all
- Argon has an extra shell that gives more shielding, so its outer electron is harder to remove
- Argon has one more proton, and its outer electron is in a full 3p subshell that is held more strongly
- Argon has fewer protons, so its outer electron is held more strongly than in chlorine
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Why is the first ionisation energy of silicon higher than that of aluminium?
- Silicon has more shielding from neutrons, which reduces the attraction on its outer electron
- Silicon has one more proton, and its outer electron is in the same 3p subshell with a greater nuclear attraction
- Silicon has an extra shell, so its outer electron is further from the nucleus
- Silicon has fewer electrons in its outer shell, so it holds them more tightly
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Which factor does NOT explain the trend in atomic radius across Period 3?
- The attraction of the outer electrons by the nucleus, which becomes stronger as more protons are added
- Similar shielding of the outer electrons by the inner shells, which stays roughly constant across the period
- A change in the number of electron shells, since all Period 3 atoms have three shells
- An increase in nuclear charge across the period, which pulls the outer electrons in more strongly each time
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Explain why the atomic radius of sodium is larger than that of chlorine.
- Sodium has more neutrons, which push the outer electrons away from the nucleus
- Sodium has more electron shells, so its outer electrons are further from the nucleus
- Sodium has fewer protons, so its nucleus pulls the outer electrons less strongly than chlorine does
- Chlorine has fewer electrons, so its atom is physically smaller in size
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Describe the general trend in melting point across Period 3 from sodium to silicon.
- It rises from sodium to silicon, then falls steadily to argon without any exceptions
- It rises from sodium to silicon, where the giant covalent structure gives the maximum
- It falls steadily from sodium to silicon, because silicon is a gas at room temperature
- It is the same for all four elements, because they all have metallic bonding
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Why is the first ionisation energy of sodium lower than that of magnesium?
- Sodium has a higher nuclear charge, so its outer electron is held less strongly than in magnesium
- Sodium has more shells than magnesium, so its outer electron is closer to the nucleus
- Sodium has a single electron in its outer 3s subshell that is held less strongly than the two in magnesium
- Sodium has more paired electrons in its outer subshell, which makes it easier to lose one
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Which statement about the melting points of phosphorus, sulfur and chlorine is correct?
- They are low because they are molecular substances with weak forces between the molecules
- They are high because they are metals with many delocalised electrons
- They are high because they are giant covalent solids with strong bonds throughout
- They are low because they are ionic solids with weak electrostatic forces
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The first ionisation energy of Na is 496 kJ/mol and of Mg is 738 kJ/mol. What is the difference between them?
- 738 kJ/mol
- 1234 kJ/mol
- 496 kJ/mol
- 242 kJ/mol
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What is the first ionisation energy of sodium, in kJ/mol?
- 578 kJ/mol
- 496 kJ/mol
- 1251 kJ/mol
- 738 kJ/mol
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