Lesson 3.2.3.1
3.2.3.1 Trends in properties Quiz: AQA Chemistry, Unit 2
20 questions
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Lesson 3.2.3.1, Trends in properties: 20 multiple choice questions for the AQA Chemistry (7405), Unit 2: Inorganic chemistry, written with Revision Ninja.
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The 20 questions
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How does the electronegativity of the halogens change down Group 7?
- It decreases, because the atoms lose electrons more easily down the group
- It stays the same, because all halogens have seven outer electrons
- It decreases, because the bonding pair is further from the nucleus and shielding increases
- It increases, because the atoms become larger and attract electrons more strongly
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Why does the boiling point of the halogens increase down Group 7?
- The molecules have stronger covalent bonds between the atoms, which need more energy to break
- The molecules have more electrons and larger London forces between them
- The molecules become smaller, so they pack together more tightly
- The molecules become more ionic, so stronger electrostatic forces hold them together
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What is the boiling point trend across the halogens F2, Cl2, Br2 and I2?
- It is the same for all four halogens
- It decreases from fluorine to iodine
- It increases from fluorine to iodine
- It increases then decreases from fluorine to iodine
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How does the oxidising ability of the halogens change down Group 7?
- It stays the same, because all halogens are diatomic molecules
- It increases, so iodine is a stronger oxidising agent than chlorine
- It increases steadily, so astatine is the weakest oxidising agent
- It decreases, so chlorine is a stronger oxidising agent than iodine
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In aqueous solution, which displacement reaction occurs?
- Br2 + 2Cl^- -> 2Br^- + Cl2
- I2 + 2Cl^- -> 2I^- + Cl2
- Cl2 + 2I^- -> 2Cl^- + I2 is not possible in water
- Cl2 + 2Br^- -> 2Cl^- + Br2
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Which reagent turns a mixture of chlorine and sodium bromide solution orange, showing that bromine has formed?
- Water, which reacts with bromide ions to form orange bromine
- Chlorine, which displaces bromide ions to form orange bromine
- Sodium hydroxide, which oxidises bromide ions to bromine
- Sodium chloride, which reacts with bromide to form orange bromine
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How does the reducing ability of the halide ions change down Group 7?
- It stays the same, because all halide ions have a 1- charge
- It decreases, so chloride is a stronger reducing agent than iodide
- It increases, so chloride is a stronger reducing agent than iodide
- It increases, so iodide is a stronger reducing agent than chloride
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What is observed when solid sodium iodide is heated with concentrated sulfuric acid?
- The sulfuric acid is reduced to sulfur dioxide only, with no iodine formed, since iodide is not oxidised by it
- Only hydrogen chloride gas is formed, with no colour change, because iodide is a weaker reducing agent than chloride
- The iodide is oxidised, giving iodine and sometimes hydrogen sulfide, with a purple vapour seen
- No reaction occurs, because iodide ions are not reactive with acid and cannot be oxidised by concentrated sulfuric acid
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Why does NaBr react with concentrated sulfuric acid to form bromine, while NaCl does not?
- Bromide ions are stronger reducing agents than chloride ions, so they are oxidised by the sulfuric acid
- Chloride ions are stronger reducing agents than bromide ions, so they are oxidised more easily
- Bromine is more stable than chlorine, so it does not form in any reaction
- Sodium chloride is a covalent compound, so it cannot react with sulfuric acid
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Which reagent is used to identify and distinguish the halide ions?
- Acidified barium chloride solution
- Litmus solution, which changes colour with each halide
- Dilute sodium hydroxide solution alone
- Acidified silver nitrate solution
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What precipitate colours are formed with acidified silver nitrate for chloride, bromide and iodide ions respectively?
- Cream, yellow and white
- White, cream and yellow
- Black, white and red
- Yellow, white and cream
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Why is the silver nitrate solution acidified in the halide test?
- To make the silver ions more reactive, so the reaction takes place much faster and the precipitate forms at once
- To react with the halide ions and make them insoluble in the mixture, so that they settle out as a solid
- To dissolve the silver halide precipitates so that they can be identified more easily by the colour change
- To remove carbonate ions, which would also form a precipitate with silver ions and confuse the result
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Why is ammonia solution added after silver nitrate in the halide test?
- To distinguish silver halides by their different solubility in ammonia
- To neutralise the acid, so that the solution becomes alkaline
- To react with the silver ions and remove them from solution completely
- To make the silver halide precipitate form more quickly
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Which silver halide dissolves in dilute aqueous ammonia?
- None of them, because all silver halides are insoluble in ammonia
- Silver chloride
- Silver iodide
- Silver bromide only in concentrated ammonia, which is the same as silver iodide
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What is the trend in solubility of the silver halides in ammonia down the group?
- It increases, so AgI dissolves most readily in ammonia
- It stays the same for all silver halides in ammonia
- It decreases, so AgCl is insoluble while AgI dissolves most readily
- It decreases, so AgI is insoluble in ammonia while AgCl dissolves most readily
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Why is fluorine not used in school laboratory studies of the halogens?
- It does not react with any halide ion, so it is of no interest in experiments
- It is a liquid at room temperature, so it cannot be measured by volume
- It is a noble gas, so it cannot take part in any reaction
- It is too dangerous and reactive to handle safely in a school laboratory
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Which sodium halide gives sulfur-containing products such as H2S and S when heated with concentrated sulfuric acid?
- Sodium iodide, because iodide is a strong reducing agent
- Sodium fluoride, because fluoride is a strong reducing agent
- Sodium chloride, because chloride is a strong reducing agent
- Sodium bromide only, because bromide is the only halide that reduces sulfuric acid
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Which halogen is the most electronegative?
- Iodine
- Fluorine
- Bromine
- Chlorine
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Which halogen is the strongest oxidising agent?
- Bromine
- Fluorine
- Iodine
- Chlorine
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Why is acidified silver nitrate chosen to identify halide ions rather than an alternative reagent?
- Silver nitrate turns the solution red whenever a halide is present, so the colour change identifies the halide ion
- Silver nitrate is the only reagent that dissolves all halide ions completely, so it is used in every halide test
- The silver halides have distinct colours and different solubilities in ammonia, which allow the halides to be distinguished
- Silver nitrate reacts with the halide ions to release a gas that can be smelt, so the halides are identified by smell
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