Lesson 3.1.6.2
3.1.6.2 Equilibrium constant Kc for homogeneous systems Quiz: AQA Chemistry, Unit 1
20 questions
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Lesson 3.1.6.2, Equilibrium constant Kc for homogeneous systems: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.
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The 20 questions
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Which expression is the correct Kc for the homogeneous equilibrium 2A(g) + B(g) <=> C(g)?
- Kc = [C]^2/([A] [B])
- Kc = [A][B]/[C]
- Kc = [C]/([A]^2 [B])
- Kc = [A]^2 [B]/[C]
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Which expression is the correct Kc for the equilibrium N2O4(g) <=> 2NO2(g)?
- Kc = [NO2]/[N2O4]
- Kc = [N2O4]/[NO2]^2
- Kc = [NO2]^2/[N2O4]
- Kc = [NO2]^2 [N2O4]
-
At equilibrium for H2(g) + I2(g) <=> 2HI(g), [H2] = 0.10, [I2] = 0.10 and [HI] = 0.80 mol dm^-3. What is Kc?
- 16
- 0.016
- 64
- 8
-
For 2SO2(g) + O2(g) <=> 2SO3(g), at equilibrium [SO2] = 0.20, [O2] = 0.10 and [SO3] = 0.50 mol dm^-3. What is Kc?
- 62.5 dm^3 mol^-1
- 250 dm^3 mol^-1
- 0.4 dm^3 mol^-1
- 2.5 dm^3 mol^-1
-
For A + B <=> C + D, the equilibrium concentrations are [A] = 0.50, [B] = 0.20, [C] = 0.40 and [D] = 0.10 mol dm^-3. What is Kc?
- 2.5
- 0.4
- 4.0
- 0.04
-
The equilibrium PCl5(g) <=> PCl3(g) + Cl2(g) has [PCl5] = 0.20, [PCl3] = 0.40 and [Cl2] = 0.40 mol dm^-3. What is Kc?
- 0.8 mol dm^-3
- 1.6 mol dm^-3
- 0.4 mol dm^-3
- 0.2 mol dm^-3
-
In an equilibrium 2HI <=> H2 + I2 in a 2 dm^3 vessel, the amounts at equilibrium are 0.4 mol HI, 0.1 mol H2 and 0.1 mol I2. What is Kc?
- 0.0625
- 0.0156
- 0.0313
- 0.2500
-
For N2(g) + 3H2(g) <=> 2NH3(g), what are the units of Kc?
- mol dm^-3
- No units, because Kc is a pure number
- dm^6 mol^-2
- dm^3 mol^-1
-
For the equilibrium A + B <=> 2C, which of the following is the units of Kc?
- dm^3 mol^-1, because the product concentration is squared while each reactant concentration appears only once
- mol^2 dm^-6, because the square of the product concentration is divided by the product of the reactant concentrations
- No units, because the number of moles of C equals the sum of A and B
- mol dm^-3, because the expression has one net mole of gas more on the product side than on the reactant side
-
Which change will change the numerical value of Kc for a reversible reaction?
- A change in temperature, because the value of Kc depends on temperature
- A change in the concentration of one of the reactants, at constant temperature
- A change in the total volume of the mixture at constant temperature
- The addition of a catalyst, at constant temperature and pressure
-
For an exothermic reversible reaction, what happens to the value of Kc when the temperature is increased?
- Kc stays the same, because only the rate of reaction changes with temperature
- Kc decreases, because the equilibrium shifts towards the reactants
- Kc becomes zero, because the reactants are fully consumed at high temperature
- Kc increases, because the equilibrium shifts towards the products
-
A student says that adding more reactant to an equilibrium mixture increases the value of Kc. Which response is correct?
- Correct, because a higher reactant concentration always increases the value of Kc at all temperatures
- Incorrect, because Kc depends only on temperature, and the equilibrium shifts to restore the same Kc
- Partly correct, because Kc rises with reactant concentration only in gas-phase equilibria
- Correct, because Kc is the ratio of reactants to products and so rises with more reactant
-
In the Kc expression for a reaction, what happens to the value of Kc if the equilibrium position moves further to the right?
- Kc increases, because the numerator product concentrations grow relative to the reactants at the same temperature
- Kc becomes negative, because the reverse reaction has started to dominate the system and reverses the sign of the constant
- Kc decreases, because the reactant concentration in the denominator becomes smaller as the equilibrium moves in the reverse direction
- Kc is unchanged, because movement along the equilibrium position does not change the value of the equilibrium constant at all
-
A reaction is catalysed. Which statement about the equilibrium constant Kc is correct?
- Kc increases, because the catalyst makes the forward reaction faster than the reverse
- Kc is unchanged, because the catalyst speeds up the forward and reverse reactions equally
- Kc decreases, because the catalyst lowers the number of molecules available to react
- Kc increases, because a catalyst always shifts the equilibrium towards the products
-
The equilibrium concentration of ester in the esterification of ethanol and ethanoic acid is found using Kc. Why must the Kc expression be written with the correct stoichiometric powers?
- The powers are needed only when the reaction is at a high temperature, not in aqueous solution
- The powers are used to convert concentration into partial pressure before the Kc expression is written
- Each concentration term must be raised to its coefficient, so the expression reflects the balanced equation
- Each concentration term must be raised to the power of the total moles, so all species are counted equally
-
For the equilibrium 2A(g) + B(g) <=> 2C(g) + D(g), which is the correct expression for Kc?
- Kc = [C]^2 [D]^2/([A]^2 [B]^2)
- Kc = [C][D]/([A][B])
- Kc = [C]^2 [D]/([A]^2 [B])
- Kc = [A]^2 [B]/([C]^2 [D])
-
A solution of ethanol and ethanoic acid reaches equilibrium with Kc about 4 at a fixed temperature. If the initial moles of reactants are doubled, what happens to Kc?
- Kc becomes 8, because the number of moles of each reactant is multiplied
- Kc remains about 4, because Kc depends only on temperature for this equilibrium
- Kc doubles, because the amount of each reactant has doubled
- Kc halves, because the extra reactant reduces the equilibrium constant
-
For N2O4(g) <=> 2NO2(g), a vessel has [N2O4] = 0.040 and [NO2] = 0.040 mol dm^-3 at equilibrium. What is Kc?
- 25 mol dm^-3
- 0.0016 mol dm^-3
- 1.0 mol dm^-3
- 0.040 mol dm^-3
-
A mixture contains 0.30 mol of A and 0.30 mol of B in 1.0 dm^3 and reaches equilibrium with 0.10 mol of C for A + B <=> C. What is Kc?
- 0.10 dm^3 mol^-1
- 0.033 dm^3 mol^-1
- 2.5 dm^3 mol^-1
- 10 dm^3 mol^-1
-
For N2O4(g) <=> 2NO2(g), Kc = 0.50 mol dm^-3 at a fixed temperature. If [N2O4] = 0.20 mol dm^-3 at equilibrium, what is [NO2]?
- 0.32 mol dm^-3
- 2.5 mol dm^-3
- 0.40 mol dm^-3
- 0.10 mol dm^-3
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