Lesson 3.1.4.4
3.1.4.4 Bond enthalpies Quiz: AQA Chemistry, Unit 1
20 questions
In partnership with Revision Ninja
Lesson 3.1.4.4, Bond enthalpies: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.
Host it live on the board and students join with a game code on their own devices, or revise alone with Free Play. The answers are revealed in the game.
The 20 questions
-
What is the mean bond enthalpy?
- The average energy needed to break one mole of a given bond in gaseous molecules, averaged over different compounds
- The energy released when one mole of gaseous ions forms from atoms, averaged across many different ionic compounds
- The energy needed to change one mole of a liquid into a gas at its normal boiling point, measured for the liquid alone
- The energy needed to break one bond in a solid lattice, measured for the bonds in a sample of salt
-
Breaking bonds is what type of process?
- Neutral
- Exothermic
- Endothermic
- Isothermal
-
Forming bonds is what type of process?
- Endothermic
- Endothermic only in solids
- Exothermic
- Zero energy
-
Which expression gives delta H using bond enthalpies?
- Sum of all bond energies in the products
- Energy of bonds broken minus energy of bonds formed
- Sum of all bond energies in the reactants only
- Energy of bonds formed minus energy of bonds broken
-
Why are mean bond enthalpies used in calculations?
- Because they measure lattice energy directly, which is the energy of the solid compound
- Because they are always exact for every molecule, so no averaging is needed in the calculation
- Because they apply only to ionic bonds, which are the only bonds with a fixed energy value
- Because the same bond has slightly different energies in different compounds
-
Which phase do mean bond enthalpy calculations apply to?
- The aqueous phase only
- The gaseous phase
- The liquid phase only
- The solid phase only
-
Why are bond enthalpy values only approximate?
- They change with temperature only in the laboratory, not in the gas phase where they are used
- They are only measured in aqueous solution, which is where most bonds are broken and formed
- They are mean values across a range of compounds containing that bond
- They ignore all of the bonds in a molecule, using just one bond type to represent the whole compound
-
Using H-H = 436, Cl-Cl = 242 and H-Cl = 431 kJ mol-1, what is delta H for H2 + Cl2 -> 2HCl?
- +184 kJ mol-1
- -678 kJ mol-1
- -1109 kJ mol-1
- -184 kJ mol-1
-
Using H-H = 436, F-F = 158 and H-F = 562 kJ mol-1, what is delta H for H2 + F2 -> 2HF?
- +530 kJ mol-1
- -1124 kJ mol-1
- -594 kJ mol-1
- -530 kJ mol-1
-
Using C-H = 413, Cl-Cl = 242, C-Cl = 328 and H-Cl = 431 kJ mol-1, what is delta H for CH4 + Cl2 -> CH3Cl + HCl?
- -759 kJ mol-1
- +104 kJ mol-1
- -655 kJ mol-1
- -104 kJ mol-1
-
Which bond needs the most energy to break: C-C (348), C=C (612) or C≡C (838) kJ mol-1?
- C=C
- C≡C
- All are equal
- C-C
-
When is a reaction endothermic according to bond enthalpy calculations?
- When the energy released forming bonds exceeds the energy absorbed, so the reaction gives out heat
- When only bond breaking releases energy, and bond making always takes in energy from the surroundings
- When the energy absorbed to break bonds is greater than the energy released when new bonds form
- When the two energies are exactly equal, so no net heat is exchanged with the surroundings
-
Using C=C = 612, H-H = 436, C-C = 348 and C-H = 413 kJ mol-1, what is delta H for C2H4 + H2 -> C2H6?
- -1048 kJ mol-1
- -1174 kJ mol-1
- +126 kJ mol-1
- -126 kJ mol-1
-
What is the enthalpy change for the formation of H2 gas from H atoms, given H-H = 436 kJ mol-1?
- +436 kJ mol-1
- -218 kJ mol-1
- +218 kJ mol-1
- -436 kJ mol-1
-
Which statement about bond breaking and making is correct?
- Breaking bonds releases energy and making bonds absorbs energy
- Both breaking and making bonds absorb energy
- Neither breaking nor making bonds involves energy
- Breaking bonds absorbs energy and making bonds releases energy
-
Why does methane have a different C-H bond enthalpy from ethane?
- Ethane has no C-H bonds, because its carbon atoms are joined only by single covalent bonds
- Mean bond enthalpies vary across compounds, so a bond's enthalpy depends on the molecule it sits in
- Methane is an ionic compound, so its C-H bonds are weaker than the bonds in covalent ethane
- C-H bonds are identical in all compounds, so methane and ethane have exactly the same bond enthalpy
-
Using N≡N = 945, H-H = 436 and N-H = 391 kJ mol-1, what is delta H for N2 + 3H2 -> 2NH3?
- +93 kJ mol-1
- -93 kJ mol-1
- -2253 kJ mol-1
- -2346 kJ mol-1
-
Why are mean bond enthalpy calculations restricted to gaseous species?
- Gases have no bonds, so the calculation can only be applied to liquids and solids in practice
- Bond enthalpies can only be measured in liquids, where the molecules are close enough to react
- Solid lattices always need water to form bonds, so only aqueous reactions can be calculated
- Bond enthalpies refer to bonds in isolated gaseous molecules, so intermolecular energies would distort the values
-
Using C=C = 612, H-Cl = 431, C-C = 348, C-H = 413 and C-Cl = 328 kJ mol-1, what is the estimated delta H for C2H4 + HCl -> C2H5Cl?
- +46 kJ mol-1
- -1089 kJ mol-1
- -1043 kJ mol-1
- -46 kJ mol-1
-
A reaction needs 1200 kJ to break bonds and releases 1350 kJ when bonds form. What is delta H?
- -2550 kJ mol-1
- +150 kJ mol-1
- -150 kJ mol-1
- +2550 kJ mol-1
Related quizzes
- Fundamental particles Quiz · 3.1.1.1 · 20 questions
- Mass number and isotopes Quiz · 3.1.1.2 · 20 questions
- Electron configuration Quiz · 3.1.1.3 · 20 questions
- Relative atomic mass and relative molecular mass Quiz · 3.1.2.1 · 20 questions
- The mole and the Avogadro constant Quiz · 3.1.2.2 · 20 questions
- The ideal gas equation Quiz · 3.1.2.3 · 20 questions
- Empirical and molecular formula Quiz · 3.1.2.4 · 20 questions
- Balanced equations and associated calculations Quiz · 3.1.2.5 · 20 questions
- Ionic bonding Quiz · 3.1.3.1 · 20 questions
- Nature of covalent and dative covalent bonds Quiz · 3.1.3.2 · 20 questions