Lesson 3.1.4.4

3.1.4.4 Bond enthalpies Quiz: AQA Chemistry, Unit 1

20 questions

In partnership with Revision Ninja

Lesson 3.1.4.4, Bond enthalpies: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.

Host it live on the board and students join with a game code on their own devices, or revise alone with Free Play. The answers are revealed in the game.

Host this setFree Play

The 20 questions

  1. What is the mean bond enthalpy?

    • The average energy needed to break one mole of a given bond in gaseous molecules, averaged over different compounds
    • The energy released when one mole of gaseous ions forms from atoms, averaged across many different ionic compounds
    • The energy needed to change one mole of a liquid into a gas at its normal boiling point, measured for the liquid alone
    • The energy needed to break one bond in a solid lattice, measured for the bonds in a sample of salt
  2. Breaking bonds is what type of process?

    • Neutral
    • Exothermic
    • Endothermic
    • Isothermal
  3. Forming bonds is what type of process?

    • Endothermic
    • Endothermic only in solids
    • Exothermic
    • Zero energy
  4. Which expression gives delta H using bond enthalpies?

    • Sum of all bond energies in the products
    • Energy of bonds broken minus energy of bonds formed
    • Sum of all bond energies in the reactants only
    • Energy of bonds formed minus energy of bonds broken
  5. Why are mean bond enthalpies used in calculations?

    • Because they measure lattice energy directly, which is the energy of the solid compound
    • Because they are always exact for every molecule, so no averaging is needed in the calculation
    • Because they apply only to ionic bonds, which are the only bonds with a fixed energy value
    • Because the same bond has slightly different energies in different compounds
  6. Which phase do mean bond enthalpy calculations apply to?

    • The aqueous phase only
    • The gaseous phase
    • The liquid phase only
    • The solid phase only
  7. Why are bond enthalpy values only approximate?

    • They change with temperature only in the laboratory, not in the gas phase where they are used
    • They are only measured in aqueous solution, which is where most bonds are broken and formed
    • They are mean values across a range of compounds containing that bond
    • They ignore all of the bonds in a molecule, using just one bond type to represent the whole compound
  8. Using H-H = 436, Cl-Cl = 242 and H-Cl = 431 kJ mol-1, what is delta H for H2 + Cl2 -> 2HCl?

    • +184 kJ mol-1
    • -678 kJ mol-1
    • -1109 kJ mol-1
    • -184 kJ mol-1
  9. Using H-H = 436, F-F = 158 and H-F = 562 kJ mol-1, what is delta H for H2 + F2 -> 2HF?

    • +530 kJ mol-1
    • -1124 kJ mol-1
    • -594 kJ mol-1
    • -530 kJ mol-1
  10. Using C-H = 413, Cl-Cl = 242, C-Cl = 328 and H-Cl = 431 kJ mol-1, what is delta H for CH4 + Cl2 -> CH3Cl + HCl?

    • -759 kJ mol-1
    • +104 kJ mol-1
    • -655 kJ mol-1
    • -104 kJ mol-1
  11. Which bond needs the most energy to break: C-C (348), C=C (612) or C≡C (838) kJ mol-1?

    • C=C
    • C≡C
    • All are equal
    • C-C
  12. When is a reaction endothermic according to bond enthalpy calculations?

    • When the energy released forming bonds exceeds the energy absorbed, so the reaction gives out heat
    • When only bond breaking releases energy, and bond making always takes in energy from the surroundings
    • When the energy absorbed to break bonds is greater than the energy released when new bonds form
    • When the two energies are exactly equal, so no net heat is exchanged with the surroundings
  13. Using C=C = 612, H-H = 436, C-C = 348 and C-H = 413 kJ mol-1, what is delta H for C2H4 + H2 -> C2H6?

    • -1048 kJ mol-1
    • -1174 kJ mol-1
    • +126 kJ mol-1
    • -126 kJ mol-1
  14. What is the enthalpy change for the formation of H2 gas from H atoms, given H-H = 436 kJ mol-1?

    • +436 kJ mol-1
    • -218 kJ mol-1
    • +218 kJ mol-1
    • -436 kJ mol-1
  15. Which statement about bond breaking and making is correct?

    • Breaking bonds releases energy and making bonds absorbs energy
    • Both breaking and making bonds absorb energy
    • Neither breaking nor making bonds involves energy
    • Breaking bonds absorbs energy and making bonds releases energy
  16. Why does methane have a different C-H bond enthalpy from ethane?

    • Ethane has no C-H bonds, because its carbon atoms are joined only by single covalent bonds
    • Mean bond enthalpies vary across compounds, so a bond's enthalpy depends on the molecule it sits in
    • Methane is an ionic compound, so its C-H bonds are weaker than the bonds in covalent ethane
    • C-H bonds are identical in all compounds, so methane and ethane have exactly the same bond enthalpy
  17. Using N≡N = 945, H-H = 436 and N-H = 391 kJ mol-1, what is delta H for N2 + 3H2 -> 2NH3?

    • +93 kJ mol-1
    • -93 kJ mol-1
    • -2253 kJ mol-1
    • -2346 kJ mol-1
  18. Why are mean bond enthalpy calculations restricted to gaseous species?

    • Gases have no bonds, so the calculation can only be applied to liquids and solids in practice
    • Bond enthalpies can only be measured in liquids, where the molecules are close enough to react
    • Solid lattices always need water to form bonds, so only aqueous reactions can be calculated
    • Bond enthalpies refer to bonds in isolated gaseous molecules, so intermolecular energies would distort the values
  19. Using C=C = 612, H-Cl = 431, C-C = 348, C-H = 413 and C-Cl = 328 kJ mol-1, what is the estimated delta H for C2H4 + HCl -> C2H5Cl?

    • +46 kJ mol-1
    • -1089 kJ mol-1
    • -1043 kJ mol-1
    • -46 kJ mol-1
  20. A reaction needs 1200 kJ to break bonds and releases 1350 kJ when bonds form. What is delta H?

    • -2550 kJ mol-1
    • +150 kJ mol-1
    • -150 kJ mol-1
    • +2550 kJ mol-1

All AQA Chemistry quizzes