Lesson 8.1.2
8.1.2 Measuring enthalpy changes Quiz: Pearson Edexcel Chemistry, Unit 8
20 questions
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Lesson 8.1.2, Measuring enthalpy changes: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 8: Energetics I, written with Revision Ninja.
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The 20 questions
-
What is the expression used to calculate the energy transferred to a known mass of water in an enthalpy experiment?
- q = m x c x delta T
- q = c x delta T / m
- q = m / c x delta T
- q = m x c / delta T
-
What is the specific heat capacity of water usually taken to be in calorimetry calculations?
- 41.8 J g-1 K-1
- 0.418 J g-1 K-1
- 2.10 J g-1 K-1
- 4.18 J g-1 K-1
-
50.0 g of water is heated by 12.0 K in an experiment. How much energy is transferred to the water, using c = 4.18 J g-1 K-1?
- 0.502 kJ
- 25.1 kJ
- 2.51 kJ
- 2508 kJ
-
In a spirit burner experiment, 2.00 g of ethanol (Mr = 46.0) heats 100 g of water by 10.0 K. What is the enthalpy of combustion of ethanol, in kJ mol-1?
- -191 kJ mol-1
- -9.61 kJ mol-1
- -96.1 kJ mol-1
- -4.18 kJ mol-1
-
Why is the experimental enthalpy of combustion of an alcohol in a spirit burner usually less exothermic than the data book value?
- The water absorbs more heat than the fuel releases, which means that the measurement is too large
- Alcohols never burn completely in air, so no heat is released in a spirit burner at all
- The data book values are measured at 100 K, which is a very different temperature from the lab
- Heat is lost to the surroundings and the apparatus, so less heat reaches the water
-
In a neutralisation experiment, 25.0 cm3 of 1.00 mol dm-3 HCl is mixed with 25.0 cm3 of 1.00 mol dm-3 NaOH. The temperature rises by 6.0 K. What is the enthalpy of neutralisation? Assume the solution has mass 50.0 g and c = 4.18 J g-1 K-1.
- -100 kJ mol-1
- -50.2 kJ mol-1
- -1.25 kJ mol-1
- +50.2 kJ mol-1
-
Which statement about recording enthalpy values from experiments is correct?
- Units are optional if the value is quoted in joules
- Both the sign and the units must be given in the final answer
- The sign is always positive in experimental results
- Only the magnitude is needed, since the sign is understood
-
Which change most reduces the percentage error in a calorimetry experiment of this type?
- Using a smaller mass of water so that less heat is absorbed by the water and the change is more visible
- Using a thinner container so that heat escapes more easily and the temperature rise is reduced
- Using a larger temperature change so that the measurement uncertainty is a smaller fraction
- Recording the temperature less often so that fewer readings are needed during the experiment
-
A student uses a polystyrene cup with no lid. Which effect is most likely to occur?
- Heat is lost to the surroundings, so the measured temperature rise is too small
- The measured temperature rise is too large because heat enters the cup
- The enthalpy change becomes exactly zero
- The mass of water increases during the experiment
-
Which method is used when an enthalpy change cannot be measured directly?
- Hess's Law or an indirect calculation using other measured enthalpy changes
- Measuring the colour change of an indicator added to the reaction mixture during the experiment
- Using a pH meter to read the heat released directly from the solution at each stage
- Counting the bubbles produced by the reaction and converting the count into an energy value
-
In an experiment, the temperature falls by 4.0 K when a dissolving salt is added to 100 g of water. What is the sign of the enthalpy change?
- Zero, because the temperature change is small
- Negative, because heat is released to the water
- Positive, because heat is absorbed from the water
- Negative, because the mass of water fell
-
A student dissolves 2.00 g of solid in 50.0 cm3 of water and the temperature falls by 2.0 K. Which assumption is needed to calculate the enthalpy change?
- The density of water is 1.00 g cm-3, so 50.0 cm3 has a mass of 50.0 g
- The solid has no mass, so the mass of the solution is taken to be the mass of the water alone
- The reaction releases exactly 2.0 J of heat to the solution, which is the value used in the calculation
- The water evaporates completely during the experiment so that no heat is retained in the solution
-
Why is an insulated container used in a calorimetry experiment?
- To make the reaction endothermic so that the temperature of the solution rises during mixing
- To reduce heat loss so that more of the energy change is transferred to the water
- To increase the speed of the reaction by holding the reagents at a constant high temperature
- To keep the reagents in the solid state so that they can be weighed accurately before the reaction
-
What is the sign and value of the enthalpy change if 0.0100 mol of a substance releases 0.5 kJ of heat?
- -50 kJ mol-1
- +0.5 kJ mol-1
- +50 kJ mol-1
- -5.0 kJ mol-1
-
A reaction releases 1.26 kJ of heat when 0.0250 mol of a reagent reacts. What is the enthalpy change in kJ mol-1?
- +50.4 kJ mol-1
- -1.26 kJ mol-1
- -31.5 kJ mol-1
- -50.4 kJ mol-1
-
What does the term 'specific heat capacity' describe?
- The mass of substance needed to absorb 1 J of energy when its temperature rises by one kelvin
- The energy needed to raise the temperature of 1 g of a substance by 1 K
- The energy needed to melt 1 mol of a substance at its melting point under standard pressure
- The energy released when 1 mol of a substance burns completely in excess oxygen at 298 K
-
In a calorimetry experiment, which quantity must be known to convert a measured energy change into an enthalpy change in kJ mol-1?
- The colour of the solution at the end of the reaction, which indicates how much heat was released
- The number of protons in the reagent molecule, which determines the energy of each bond
- The pH of the water before the reaction, which sets the starting energy of the solution
- The amount in moles of the limiting reactant or fuel
-
A graph of temperature against time is extrapolated in a displacement reaction. What is the purpose of this extrapolation?
- To estimate the temperature change that would have occurred without heat loss during the reaction
- To calculate the pH of the final solution from the temperature readings taken at each point
- To determine the molar mass of the metal by measuring the mass lost during the displacement reaction
- To find the rate constant of the reaction from the gradient of the extrapolated line on the graph
-
Which of the following is a valid source of uncertainty in an enthalpy experiment?
- The number of significant figures in the specific heat capacity constant only
- The colour of the calorimeter
- The atomic mass of hydrogen in the water
- The thermometer reading, which is limited to about 0.5 K
-
Which statement about the energy transfer in a calorimetry experiment is correct?
- The energy transferred equals the mass of the reactant multiplied by its molar mass, giving the heat released
- The energy transferred to the water equals m c delta T, assuming the water absorbs all the heat from the reaction
- The energy transferred is always equal to the molar volume of the gas produced in the reaction
- The energy transferred equals delta T divided by the specific heat capacity of the solution used
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