Lesson 8.1.1
8.1.1 Standard enthalpy changes and enthalpy level diagrams Quiz: Pearson Edexcel Chemistry, Unit 8
20 questions
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Lesson 8.1.1, Standard enthalpy changes and enthalpy level diagrams: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 8: Energetics I, written with Revision Ninja.
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The 20 questions
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What are standard conditions for enthalpy change data?
- 1 atm and 0 K, the conditions at absolute zero where all molecular motion has stopped
- 101.3 kPa and 273 K, the conditions of one atmosphere at the normal freezing point of water
- 10 kPa and 500 K, a low pressure and high temperature used in many industrial gas reactions
- 100 kPa and a specified temperature, usually 298 K
-
What is meant by the enthalpy change of a reaction?
- The heat energy change at constant volume only
- The energy needed to start a reaction
- The total mass of products formed in a reaction
- The heat energy change at constant pressure
-
Which definition matches the standard enthalpy change of formation?
- The enthalpy change when one mole of a compound is formed from its elements in their standard states
- The energy needed to break one mole of bonds in a molecule in the gas phase at standard conditions
- The enthalpy change when one mole of acid reacts with one mole of alkali to form one mole of water
- The enthalpy change when one mole of a compound is burned completely in oxygen to form carbon dioxide and water
-
What is the standard enthalpy change of formation of an element in its standard state?
- Zero
- Equal to its ionisation energy
- Equal to its bond enthalpy
- Always negative
-
Which definition matches the standard enthalpy change of combustion?
- The enthalpy change when one mole of a substance is burned completely in oxygen under standard conditions
- The enthalpy change when one mole of a compound is formed from its elements in their standard states
- The enthalpy change when one mole of water is formed from an acid and an alkali in a neutralisation
- The energy change when one mole of gas is ionised by removal of an electron in the gas phase
-
What is the standard enthalpy change of neutralisation when one mole of water is formed from a strong acid and a strong alkali?
- About -57 kJ mol-1
- About +57 kJ mol-1
- About -286 kJ mol-1
- About -890 kJ mol-1
-
In an enthalpy level diagram for an exothermic reaction, where is the products level drawn relative to the reactants?
- Higher than the reactants level
- Lower than the reactants level
- At the same level
- Above the activation energy line only
-
A reaction has an enthalpy change of +50 kJ mol-1. Which statement is correct?
- The reaction is exothermic and the products have lower enthalpy than the reactants, so energy is released
- The activation energy is 50 kJ mol-1, which is the energy needed to start the reaction in the flask
- The reaction is catalysed and the products have less energy than the reactants because a catalyst is present
- The reaction is endothermic and the products have higher enthalpy than the reactants
-
Which statement about the enthalpy level diagram is correct?
- Activation energy is not shown on an enthalpy level diagram, but is shown on a reaction profile
- The activation energy is always shown on an enthalpy level diagram as a labelled arrow between the two levels
- Enthalpy level diagrams show the rate of reaction directly by the spacing of the energy levels on the axis
- Reaction profile diagrams never show enthalpy change, which appears only on enthalpy level diagrams
-
The enthalpy of combustion of methane is -890 kJ mol-1. How much heat is released when 4.00 g of methane (Mr = 16.0) is burned completely?
- 3560 kJ
- 223 kJ
- 55.6 kJ
- 890 kJ
-
Which standard enthalpy change is defined for the reaction C(graphite) + O2(g) -> CO2(g)?
- Enthalpy of atomisation, because carbon is converted into a gas of single atoms in the reaction
- Enthalpy of neutralisation, because carbon reacts with oxygen to form a salt in the reaction mixture
- Enthalpy of ionisation, because electrons are removed from the carbon atoms in the reaction
- Enthalpy of combustion of graphite and of formation of CO2 both apply, because the same equation fits both definitions
-
What is the sign of the enthalpy change for the neutralisation of an acid by an alkali?
- Positive, because water is formed
- Negative, because heat is released to the surroundings
- Zero, because neutralisation is an equilibrium
- Positive, because heat is absorbed from the surroundings
-
Which standard state is defined for chlorine in its standard enthalpy of formation?
- Cl-(aq), a chloride ion in solution
- Cl2(l), liquid chlorine
- Cl(g), a single chlorine atom
- Cl2(g), the gas at 100 kPa and 298 K
-
For the enthalpy of formation of water, which equation is correct?
- H2(g) + 1/2 O2(g) -> H2O(l)
- 2H2(g) + O2(g) -> 2H2O(l)
- H2O(l) -> H2(g) + 1/2 O2(g)
- H(g) + O(g) -> H2O(l)
-
Which equation represents the standard enthalpy of combustion of ethanol?
- C2H5OH(l) -> C2H4(g) + H2O(l)
- 2C2H5OH(l) + 6O2(g) -> 4CO2(g) + 6H2O(l)
- C2H5OH(l) + O2(g) -> CH3CHO(l) + H2O(l)
- C2H5OH(l) + 3O2(g) -> 2CO2(g) + 3H2O(l)
-
What is the enthalpy change of a reaction that gives 20.0 kJ of heat released per 0.100 mol of reactant?
- +200 kJ mol-1
- -200 kJ mol-1
- -2.00 kJ mol-1
- -20.0 kJ mol-1
-
Which statement about a standard enthalpy change is correct?
- It applies only to gases at very high temperature
- It is measured in joules per gram
- It is quoted with a sign and units, such as -285.8 kJ mol-1
- It is always a positive value
-
What information must be shown on an enthalpy level diagram for an exothermic reaction?
- The activation energy between the reactants and products levels, drawn as a separate arrow above the peak
- The number of moles of catalyst used in the reaction, which must be recorded on the diagram
- The reactants above the products, with an arrow showing a negative enthalpy change
- The volume of gas produced at 298 K, which should be shown on the vertical axis of the diagram
-
The standard enthalpy of formation of carbon dioxide is -394 kJ mol-1. What does this value mean?
- Burning one mole of carbon absorbs 394 kJ of energy from the surroundings in the reaction vessel
- The bond enthalpy of C=O is 394 kJ mol-1, which is the energy needed to break one mole of the bond
- Carbon dioxide is 394 times less stable than oxygen, so it decomposes readily at room temperature
- Forming one mole of CO2 from carbon and oxygen releases 394 kJ at standard conditions
-
Which standard enthalpy change is defined for a reaction of one mole of acid with one mole of alkali to form water?
- Standard enthalpy of atomisation
- Standard enthalpy of combustion
- Standard enthalpy of formation
- Standard enthalpy of neutralisation
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