Lesson 7B.1
7B.1 Identifying functional groups from IR spectra Quiz: Pearson Edexcel Chemistry, Unit 7
20 questions
In partnership with Revision Ninja
Lesson 7B.1, Identifying functional groups from IR spectra: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 7: Modern Analytical Techniques I, written with Revision Ninja.
Host it live on the board and students join with a game code on their own devices, or revise alone with Free Play. The answers are revealed in the game.
The 20 questions
-
Which absorption is characteristic of the O-H group in an alcohol?
- An absorption around 700 cm-1 only
- A broad absorption around 3200 to 3550 cm-1
- A sharp absorption around 1700 cm-1
- A sharp absorption around 1650 cm-1 only
-
Which absorption is most characteristic of the C=O group in a ketone?
- A strong absorption around 1700 to 1750 cm-1
- A broad absorption around 2500 to 3300 cm-1
- A medium absorption around 1620 to 1680 cm-1
- A sharp absorption around 3300 to 3500 cm-1
-
Which feature distinguishes a carboxylic acid from an aldehyde in an IR spectrum?
- An absorption below 1000 cm-1 only, which identifies the acid by its fingerprint region alone
- A C=C absorption at 1650 cm-1 that shows the presence of a double bond in the molecule
- A sharp absorption at 3300 cm-1 from N-H bonds that is present in every carboxylic acid spectrum
- A very broad O-H absorption from about 2500 to 3300 cm-1, overlapping the C-H stretches
-
Which absorption is characteristic of a C=C stretch in an alkene?
- A broad absorption around 3200 to 3550 cm-1
- A sharp absorption at 3300 to 3500 cm-1 only
- A strong absorption around 1700 to 1750 cm-1
- A medium absorption around 1620 to 1680 cm-1
-
Which IR absorption indicates an N-H bond in a primary amine?
- A broad absorption around 2500 to 3300 cm-1 only
- A strong absorption around 1000 cm-1 only
- A strong absorption around 1700 cm-1
- A medium absorption around 3300 to 3500 cm-1
-
Which wavenumber range is characteristic of C-H stretching in alkanes?
- About 2850 to 3000 cm-1
- About 1700 to 1750 cm-1
- About 3200 to 3550 cm-1
- About 1620 to 1680 cm-1
-
Which absorption in an aldehyde spectrum helps distinguish it from a ketone?
- A sharp C=C stretch at 1650 cm-1 that shows the presence of an alkene in the molecule
- Two weak C-H stretches near 2700 and 2800 cm-1 from the CHO group
- A broad O-H stretch at 3300 cm-1 that shows the presence of an alcohol in the sample
- A strong C-Cl stretch near 750 cm-1 that shows a halogen is bonded to the carbon chain
-
A compound shows a strong sharp absorption at 1715 cm-1 and a very broad band from 2500 to 3300 cm-1. What is it most likely to be?
- An alcohol
- An alkene
- A carboxylic acid
- A primary amine
-
Which absorption shows the presence of a C=O group in an ester?
- A strong absorption around 1735 to 1750 cm-1
- An absorption at 1650 cm-1 only, which shows the presence of a carbon-carbon double bond
- A weak absorption at 2750 cm-1 that shows the presence of a C-H bond bonded to oxygen
- A broad absorption at 3300 cm-1 that shows the presence of an O-H group in the molecule
-
Which compound would show a broad absorption at 3200 to 3550 cm-1 and a C-O absorption near 1050 cm-1?
- Ethanal
- Ethene
- Ethanol
- Ethane
-
Which statement about infrared spectroscopy is correct?
- IR absorptions arise from bonds vibrating at characteristic frequencies, which identify functional groups
- IR radiation is used to separate ions by mass in the instrument before detection
- IR spectra give the relative molecular mass directly from the highest peak in the spectrum
- IR spectra show the number of protons in each chemical environment in the molecule
-
In an IR spectrum, which region is most useful for identifying functional groups rather than the whole molecule?
- The region at exactly 1000 cm-1 only
- Above about 1500 cm-1
- The baseline between peaks
- Below about 500 cm-1 only
-
Which wavenumber range is characteristic of a C-H stretch in an alkene or aromatic structure, slightly above 3000 cm-1?
- About 3300 to 3500 cm-1 only
- About 1700 to 1750 cm-1
- About 2500 to 3300 cm-1 only
- About 3000 to 3100 cm-1
-
Which compound shows a C=O stretch around 1715 cm-1 but no broad O-H band?
- Propanoic acid
- Propene
- Propanone
- Propan-1-ol
-
A compound has IR absorptions at 3350 cm-1 (broad) and 1050 cm-1 but no peak at 1700 cm-1. Which compound best fits?
- Propene
- Propan-2-ol
- Propanone
- Propanal
-
What bond vibration gives rise to the IR absorption near 1650 cm-1 in an alkene?
- C=C stretching
- C-H bending in an alkane
- C-Cl stretching
- O-H stretching in an alcohol
-
Which IR feature best supports the identity of an amine rather than an alcohol?
- N-H stretching absorptions around 3300 to 3500 cm-1, which are sharper than O-H bands
- A broad band from 2500 to 3300 cm-1 that shows the presence of a carboxylic acid group
- An absorption only below 800 cm-1, which identifies the compound from its fingerprint region
- A strong band at 1700 cm-1 that shows the presence of a carbonyl group in the molecule
-
Which combination of IR features is expected for propanoic acid, CH3CH2COOH?
- A sharp O-H band near 3600 cm-1 and no C=O band, which is typical of a free alcohol
- A N-H band near 3350 cm-1 and a strong C-Cl band, which is typical of a chloro amine
- A broad O-H band from 2500 to 3300 cm-1 and a strong C=O band near 1710 cm-1
- A C=C band near 1650 cm-1 and no O-H band, which is typical of an unsaturated hydrocarbon
-
A student records an IR spectrum with no absorption between 3200 and 3550 cm-1 and no absorption at 1700 cm-1. Which compound is most likely?
- Hexane
- Butan-1-amine
- Ethanoic acid
- Ethanol
-
Which region of the IR spectrum contains the C-O single bond stretch used to support an alcohol identification?
- Around 3300 to 3500 cm-1
- Around 1000 to 1300 cm-1
- Around 2850 to 3000 cm-1
- Around 1620 to 1680 cm-1
Related quizzes
- Sub-atomic particles, isotopes and relative masses Quiz · 1.1.1 · 20 questions
- Dynamic equilibrium and the equilibrium constant Kc Quiz · 10.1.1 · 20 questions
- Kp and partial pressures Quiz · 11.1.1 · 20 questions
- Brønsted-Lowry acids, bases and conjugate pairs Quiz · 12.1.1 · 20 questions
- Lattice energy and Born-Haber cycles Quiz · 13A.1 · 20 questions
- Standard electrode potentials and the hydrogen electrode Quiz · 14.1.1 · 20 questions
- Electronic configurations and oxidation states Quiz · 15A.1 · 20 questions
- Rate equations and orders of reaction Quiz · 16.1.1 · 20 questions
- Chirality, optical isomers and racemic mixtures Quiz · 17A.1 · 20 questions
- Bonding and stability of benzene Quiz · 18A.1 · 20 questions