Lesson 4B.1
4B.1 Group 7 trends and halogen reactions Quiz: Pearson Edexcel Chemistry, Unit 4
20 questions
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Lesson 4B.1, Group 7 trends and halogen reactions: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 4: Inorganic Chemistry and the Periodic Table, written with Revision Ninja.
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The 20 questions
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How do melting temperatures of the halogens change down Group 7?
- They increase, because the halogens become ionic in character as the group is descended
- They increase, because larger molecules have stronger London forces
- They are the same for all halogens, because all of them exist as diatomic molecules at room temperature
- They decrease, because larger molecules are more reactive and so break apart more readily on heating
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How does electronegativity of Group 7 elements change down the group?
- It increases, because the atoms get larger and so attract the bonding electrons more strongly overall
- It is the same for all halogens, because they all have seven electrons in their outer shell of the atom
- It increases, because there are more protons per atom as the group is descended and so attraction rises
- It decreases, because the bonding pair is further from the nucleus with more shielding
-
Why does the reactivity of halogens decrease down Group 7?
- Atoms form weaker bonds with each other further down the group, which makes them less reactive as oxidising agents
- Atoms gain electrons less easily because they are smaller, so the incoming electron is held more strongly by the nucleus
- Atoms have higher electronegativity further down the group, which makes them less willing to gain electrons
- Atoms are larger and harder to reduce, because the incoming electron is further from the nucleus and more shielded
-
What happens when chlorine water is added to aqueous potassium bromide?
- A green gas is released
- The solution turns orange, because bromine is displaced
- The solution turns colourless, because chlorine is oxidised
- A white precipitate forms immediately
-
Which equation shows the displacement of bromide by chlorine?
- Cl2 + Br- -> ClBr + Cl-
- Cl2 + 2Br- -> 2Cl- + Br2
- Cl2 + 2Br- -> 2ClBr
- Br2 + 2Cl- -> 2Br- + Cl2
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What colour is iodine dissolved in an organic solvent such as hexane?
- Colourless, because the iodine molecules dissolve completely and do not colour the organic solvent at all
- Violet or purple
- Green, which is the colour seen when chlorine water is added to an organic solvent in the test
- Yellow, which is the characteristic colour of bromine dissolved in an organic solvent such as hexane
-
What is the oxidation number change when chlorine reacts with a Group 1 metal?
- -1 to 0
- +1 to 0
- 0 to -1
- 0 to +1
-
Which equation shows the disproportionation of chlorine with water?
- Cl2 + H2O -> HCl + HOCl
- Cl2 + 2H2O -> 2HCl + H2O2
- Cl2 + H2O -> HCl + HClO2
- Cl2 + H2O -> 2HCl + O2
-
Which product forms when chlorine reacts with cold, dilute aqueous sodium hydroxide?
- Sodium hydride, which forms because chlorine reduces the sodium hydroxide to a hydride under these conditions
- Sodium chlorate(V), NaClO3, which forms when chlorine reacts with cold dilute sodium hydroxide solution
- Sodium chloride only, because chlorine reacts with cold alkali by simple displacement to form chloride
- Sodium chlorate(I), NaClO, which is bleach
-
What is formed by chlorine reacting with hot concentrated sodium hydroxide?
- Sodium chloride and oxygen
- Sodium chloride and sodium chlorate(V)
- Sodium hypochlorite and hydrogen
- Sodium chloride and sodium chlorate(I) only
-
Why is chlorine added to drinking water?
- It forms HOCl, which kills bacteria in water treatment
- It raises the pH of the water so that it becomes less acidic and more pleasant to drink for the consumer
- It converts water into hydrogen peroxide, which then destroys all the bacteria in the water supply
- It removes dissolved metal ions directly from the water by precipitating them out of the solution
-
Which Group 1 halide with concentrated sulfuric acid gives hydrogen iodide that is further reduced to iodine?
- Sodium fluoride
- Sodium chloride
- Sodium bromide
- Sodium iodide
-
What is the order of reducing ability of the hydrogen halides?
- HBr > HI > HCl
- HI > HBr > HCl
- HCl > HBr > HI
- HF > HCl > HBr
-
Which precipitate forms when silver nitrate is added to aqueous chloride ions?
- Yellow silver iodide
- White silver chloride
- Cream silver bromide
- Green silver fluoride
-
Which silver halide dissolves in dilute aqueous ammonia?
- Silver chloride
- Silver iodide
- Silver fluoride
- Silver bromide
-
Which silver halide is insoluble even in concentrated aqueous ammonia?
- Silver iodide
- Silver bromide
- Silver chloride
- Silver nitrate
-
What is formed when hydrogen chloride gas reacts with ammonia gas?
- Nitrogen, which is released as a brown gas when the hydrogen chloride reacts with the ammonia gas
- Ammonium chloride, which gives white fumes
- Ammonium hydroxide, which is a colourless solution formed when the two gases dissolve in water together
- Hydrogen chloride only, because ammonia does not react with the gas and simply mixes with it
-
Which statement about hydrogen halides dissolved in water is correct?
- They form alkaline solutions, because the hydrogen halides accept protons from the water they dissolve in
- They form neutral solutions because they are covalent, so they do not release any hydrogen ions into water
- They form acidic solutions, with HCl being a strong acid
- They are all weak acids of the same strength, because they all dissociate only partially in the water
-
Predict the physical state of astatine at room temperature.
- Gas
- Vapour
- Liquid
- Solid
-
Why is fluorine the most reactive halogen?
- It has the lowest electronegativity of the halogens, so it readily gives up its electrons to other atoms
- It has the highest melting temperature of the halogens, which reflects its strong bonds and high reactivity
- It has the largest atomic radius of the halogens, so its outer electrons are the most easily shared with others
- It has the highest electronegativity and a weak F-F bond that is easily broken
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