Lesson 17C.3

17C.3 Polyesters Quiz: Pearson Edexcel Chemistry, Unit 17

20 questions

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Lesson 17C.3, Polyesters: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 17: Organic Chemistry II, written with Revision Ninja.

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The 20 questions

  1. What type of polymerisation forms polyesters?

    • Free-radical polymerisation of alkenes only, which needs a peroxide initiator to start the chain reaction
    • Ionic polymerisation with no by-products, carried out at low temperature in a dry, inert solvent
    • Addition polymerisation, with no molecules lost as each monomer unit joins the growing polymer chain
    • Condensation polymerisation, with a small molecule such as water eliminated at each link
  2. Which two monomers are used to make a polyester?

    • Two alkenes with a catalyst
    • Two monoalcohols and an alkene
    • A dicarboxylic acid and a diol
    • A diamine and a dicarboxylic acid
  3. What small molecule is eliminated when a polyester forms from a dicarboxylic acid and a diol?

    • Ammonia
    • Carbon dioxide
    • Hydrogen chloride
    • Water
  4. Which link is present in the backbone of a polyester?

    • The ether link, -O-, between two carbon atoms
    • The amide link, -CONH-
    • The ester link, -COO-
    • The peptide link, -CONH- joining amino acids
  5. Which pair of monomers makes poly(ethylene terephthalate)?

    • Ethanoic acid and ethane-1,2-diol, joined as a simple ester
    • Benzene-1,4-dicarboxylic acid and ethane-1,2-diol
    • Ethene and benzene-1,4-diol, joined across the double bond of ethene
    • Ethane-1,2-diamine and hexanedioic acid, joined as an amide link
  6. What is the repeat unit of a polyester made from hexanedioic acid and butane-1,4-diol?

    • -[CO(CH2)4CO-O(CH2)4O]-, containing two ester links per unit
    • -[C6H4-COO]- with one acid link per unit, formed from a benzene ring and a single carboxyl group
    • -[CO(CH2)4CO]- with a diamine link per unit, formed by losing ammonia from each joining step
    • -[CH2CH2O]- with one ester link per unit, formed from a single monomer with an acid group
  7. Why are polyesters susceptible to hydrolysis?

    • They contain amide links that are easily cleaved by water
    • They contain ionic bonds that dissolve in water
    • The polymer chains contain double bonds that react with water
    • The ester links can be broken by water, especially in acid or alkali
  8. A polyester is made from 1.0 mol of a dicarboxylic acid and 1.0 mol of a diol, with complete reaction. How many moles of water are eliminated per mole of repeat unit?

    • 4
    • 0
    • 2
    • 1
  9. Why is a polyester described as a condensation polymer?

    • It forms by adding monomers across double bonds without losing any atoms
    • It forms only from monomers that contain a benzene ring
    • It forms by cross-linking existing polymer chains with heat
    • It forms by joining monomers while releasing a small molecule
  10. What is the functional group that links the monomer units of nylon?

    • A nitrile group, -CN
    • An amide link, -CONH-
    • An ether link, -O-
    • An ester link, -COO-
  11. Which monomers form a polyester whose repeat unit contains a benzene ring?

    • Propan-1-ol and propanoic acid, which give a simple ester with no repeating unit at all
    • Benzene-1,4-dicarboxylic acid and a diol
    • Ethanoic acid and a diol, which gives a polyester with a single methyl group in each unit
    • Hexane-1,6-diamine and a diacid, which gives a polyamide with no ester links in the chain
  12. Which property of polyesters is affected by the length of the diol chain?

    • The number of carbon atoms in the benzene ring
    • Flexibility and melting temperature of the polymer
    • Density of the monomers before polymerisation
    • Colour, since the diol is responsible for the colour of the polymer
  13. A polyester has a relative repeat unit mass of 192. How many repeat units make up a molecule with a relative molecular mass of 19 200?

    • 100
    • 200
    • 10
    • 1000
  14. Which statement describes the condensation polymerisation step in polyester formation?

    • A nitrogen atom attacks a carbonyl group, releasing ammonia as the amide link forms in the chain
    • A hydroxyl group from the alcohol reacts with a carboxyl group from the acid, releasing water
    • Two alkene groups add together across the double bond and form a single bond, with no atoms lost
    • A chlorine atom replaces a hydrogen atom on the aromatic ring, releasing hydrogen chloride as a gas
  15. Why does a polyester have a lower melting temperature than a polymer with stronger intermolecular forces?

    • Its ester groups give dipole-dipole forces, which are weaker than hydrogen bonding between amide groups
    • Its ester groups form strong ionic bonds between chains, which hold the polymer together more tightly
    • It has no intermolecular forces at all between its chains, so the chains slide apart when heated
    • It has more covalent cross-links per chain than polyamides, which makes the polymer easier to melt
  16. What is a consequence of the repeat unit containing two ester links from a diacid and a diol?

    • The polymer is formed only at very high pressure in the absence of water
    • The polymer contains an amine group at each end of the chain
    • The polymer has no regular structure and cannot crystallise
    • The polymer chain has a regular, repeating pattern of ester groups along its length
  17. Which molecule is a monomer used to make a polyester in industry?

    • Ethane-1,2-diol
    • Ethanamide
    • Ethanenitrile
    • Ethene
  18. Which compound is the diacid monomer used to make poly(ethylene terephthalate)?

    • Butanedioic acid, a dicarboxylic acid with four carbons in its chain
    • Benzene-1,4-dicarboxylic acid
    • Ethanedioic acid, a dicarboxylic acid with two carbons in its chain
    • Benzene-1,2-diol, a diol with the two hydroxyl groups on adjacent carbons
  19. A polyester has a repeat unit molar mass of 192 g mol-1. What is the molar mass of a chain with 50 repeat units?

    • 960 g mol-1
    • 9600 g mol-1
    • 19 200 g mol-1
    • 3840 g mol-1
  20. What mass of water is eliminated for each mole of ester link formed in a polycondensation?

    • 36 g, the molar mass of two moles of water
    • 18 g, the molar mass of one mole of water
    • 44 g, the molar mass of one mole of carbon dioxide
    • 2 g, the molar mass of one mole of hydrogen

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