Lesson 14.2.1
14.2.1 Storage cells and hydrogen-oxygen fuel cells Quiz: Pearson Edexcel Chemistry, Unit 14
20 questions
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Lesson 14.2.1, Storage cells and hydrogen-oxygen fuel cells: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 14: Redox II, written with Revision Ninja.
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The 20 questions
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What is a storage cell?
- A cell that can be recharged by reversing the cell reaction with an external electrical supply
- A cell that cannot be recharged and releases its stored energy only once, then must be discarded
- A cell that produces hydrogen gas as its only product, which is then stored for later use
- A cell that stores electrons permanently in an electrode, so that no chemical reaction takes place
-
What are the electrodes and electrolyte of a lead-acid storage cell?
- Nickel and cadmium electrodes in aqueous potassium hydroxide
- Lead and lead(IV) oxide electrodes in sulfuric acid
- Hydrogen and oxygen electrodes in phosphoric acid
- Zinc and manganese dioxide electrodes in potassium hydroxide
-
What happens to the sulfuric acid concentration of a lead-acid cell during discharge?
- It decreases, because sulfate is used up as lead(II) sulfate forms
- It increases, because lead(II) sulfate dissolves in the acid
- It increases, because water is consumed in the reaction
- It remains exactly unchanged throughout discharge
-
What is a fuel cell?
- A cell whose electrodes are consumed and must be replaced regularly, with the fuel supply stopped
- A cell in which a fuel and oxygen react continuously, converting chemical energy directly into electrical energy
- A cell that uses only solar energy to split water into hydrogen and oxygen gases at the anode
- A cell that stores electricity from a mains supply as chemical energy and releases it on demand
-
What is the only product of a hydrogen-oxygen fuel cell in its overall reaction?
- Ammonia
- Hydrogen peroxide
- Carbon dioxide
- Water
-
What is the anode reaction of a hydrogen-oxygen fuel cell with an acidic electrolyte?
- 2H+ + 2e- gives H2
- H2O gives O2 + 4H+ + 4e-
- O2 + 4H+ + 4e- gives 2H2O
- H2 gives 2H+ + 2e-
-
What is the approximate emf of one lead-acid cell?
- About 2.0 V
- About 1.2 V
- About 4.5 V
- About 0.8 V
-
What is the cathode reaction in an acidic hydrogen-oxygen fuel cell?
- H2 gives 2H+ + 2e-
- O2 + 4H+ + 4e- gives 2H2O
- 2H2O gives O2 + 4H+ + 4e-
- O2 + 2H2O + 4e- gives 4OH-
-
What is the anode reaction in an alkaline hydrogen-oxygen fuel cell?
- 2H+ + 2e- gives H2
- O2 + 2H2O + 4e- gives 4OH-
- H2 + 2OH- gives 2H2O + 2e-
- H2O + e- gives OH- + H
-
What is the theoretical emf of a hydrogen-oxygen fuel cell at standard conditions?
- 2.46 V
- 1.23 V
- 0.00 V
- -1.23 V
-
Which of these is a hydrogen-rich fuel used in fuel cells?
- Methanol, CH3OH
- Nitrogen gas
- Argon
- Neon
-
During recharging of a lead-acid cell, which electrode acts as the cathode?
- The sulfuric acid, which is reduced to hydrogen
- The lead(IV) oxide electrode, where Pb is reduced
- The lead electrode, where PbSO4 is reduced back to Pb
- Both electrodes act as anodes during charging
-
Why can a fuel cell be more efficient than a combustion engine?
- It burns the fuel at a higher temperature than a combustion engine, which gives a greater power output
- It converts chemical energy directly to electrical energy without the heat step limited by the Carnot cycle
- It produces more heat than a combustion engine from the same fuel, which is then used to drive the cell
- Combustion engines do not produce any useful energy from the fuels they burn in normal operation
-
In an acidic hydrogen-oxygen fuel cell, which way do electrons flow?
- From the oxygen electrode to the hydrogen electrode through the external circuit, against the flow of protons
- From the hydrogen (anode) electrode through the external circuit to the oxygen (cathode) electrode
- Electrons do not move at all, because only the H+ ions carry the current through the electrolyte
- Through the electrolyte from the cathode to the anode, carried by the mobile hydrogen ions
-
Using E-zero(O2/OH-) = +0.40 V and E-zero(H2O/H2) = -0.83 V, what is the emf of an alkaline hydrogen-oxygen fuel cell?
- -0.43 V
- +1.23 V
- +2.46 V
- +0.43 V
-
How many moles of electrons are transferred per mole of H2 and per mole of O2 in the fuel cell?
- 2 mol per mole of H2 and 2 mol per mole of O2
- 2 mol per mole of H2 and 4 mol per mole of O2
- 1 mol per mole of H2 and 2 mol per mole of O2
- 4 mol per mole of H2 and 2 mol per mole of O2
-
Which statement about the lead-acid storage cell is correct?
- Its theoretical emf is 0 V, so it can only store energy and never deliver a usable voltage
- It has no electrolyte, so the cell never needs replacing and the electrodes do not change at all
- It is not rechargeable and produces hydrogen gas at the anode, which is then released from the cell
- It is rechargeable, but its electrodes are consumed and the electrolyte is depleted during discharge
-
A student says hydrogen fuel cells produce no pollution at the point of use. Which evaluation is best?
- True, because they also release no heat at all, so the cell is completely clean and efficient
- Largely true at the point of use, because the only product is water, although hydrogen production may emit CO2
- False, because they emit carbon dioxide as the main product, which is released directly from the fuel cell
- False, because they produce ammonia as the main product, which is released into the air at the cathode
-
What is the overall reaction of a hydrogen-oxygen fuel cell?
- 2H2O gives 2H2 + O2
- H2 + O2 gives H2O2
- H2 + O2 gives 2OH-
- 2H2 + O2 gives 2H2O
-
How many moles of electrons flow through the external circuit when 2.0 mol of H2 is consumed in a hydrogen-oxygen fuel cell?
- 8.0 mol
- 4.0 mol
- 1.0 mol
- 2.0 mol
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