Lesson 11.1.1
11.1.1 Kp and partial pressures Quiz: Pearson Edexcel Chemistry, Unit 11
20 questions
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Lesson 11.1.1, Kp and partial pressures: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 11: Equilibrium II, written with Revision Ninja.
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The 20 questions
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What is the partial pressure of a gas in a mixture?
- The pressure of the gas at standard temperature only
- The volume of the gas as a fraction of total volume
- The total pressure of the mixture divided by the number of gases
- The pressure that gas would exert if it alone occupied the container
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How is the partial pressure of a gas calculated from its mole fraction?
- Partial pressure = mole fraction + total pressure
- Partial pressure = mole fraction x molar mass
- Partial pressure = total pressure / mole fraction
- Partial pressure = mole fraction x total pressure
-
For the equilibrium N2O4(g) ⇌ 2NO2(g), what is the expression for Kp?
- Kp = p(NO2)^2 / p(N2O4)
- Kp = p(NO2)^2 x p(N2O4)
- Kp = p(NO2) / p(N2O4)
- Kp = p(N2O4) / p(NO2)^2
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What are the usual units of Kp when partial pressures are given in atm?
- Always mol dm-3, because partial pressures are converted to concentrations before Kp is calculated
- Depends on the reaction, given as atm to the power of the change in gas moles
- Always Pa, because pressure in the SI system is used throughout all gas equilibrium calculations
- Always dimensionless, because the partial pressures are divided and the units cancel in every case
-
In a mixture at total pressure 2.00 atm, NO2 has mole fraction 0.50. What is the partial pressure of NO2?
- 1.00 atm
- 4.00 atm
- 0.50 atm
- 2.00 atm
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For the equilibrium N2O4 ⇌ 2NO2, partial pressures at equilibrium are p(N2O4) = 0.50 atm and p(NO2) = 1.00 atm. What is Kp?
- 0.50 atm
- 0.67 atm
- 2.00 atm
- 4.00 atm
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For the equilibrium 2SO2(g) + O2(g) ⇌ 2SO3(g), partial pressures are p(SO2) = 0.40 atm, p(O2) = 0.20 atm and p(SO3) = 0.80 atm. What is Kp?
- 20 atm-1
- 2.5 atm
- 0.05 atm-1
- 0.40 atm-1
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Which statement about Kp in a heterogeneous equilibrium is correct?
- Solids are included as their molar mass, which converts the expression into a mass ratio
- Solids are included with their partial pressures, since they also exert a vapour pressure in the vessel
- Solids and liquids are omitted from Kp because their activities are constant
- Pure liquids are included as their mole fractions, which are multiplied together in the expression
-
For the equilibrium CaCO3(s) ⇌ CaO(s) + CO2(g), what is the expression for Kp?
- Kp = p(CaO) / p(CaCO3)
- Kp = p(CaO) x p(CO2) / p(CaCO3)
- Kp = p(CO2)
- Kp = p(CaCO3) / p(CO2)
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A gaseous equilibrium has Kp = 4.0 atm for A(g) ⇌ 2B(g). If p(A) = 0.50 atm, what is p(B) at equilibrium?
- 1.41 atm
- 2.00 atm
- 0.25 atm
- 8.0 atm
-
Which statement about Kp is correct?
- Kp changes whenever the total pressure changes, so its value depends on the pressure of the mixture
- Kp changes with the amount of catalyst added, so a larger catalyst mass gives a larger value
- Kp is always equal to one for gases, because the partial pressures cancel in every equilibrium
- Kp is a value for a given equilibrium at a fixed temperature
-
What is the relationship between Kp and Kc for a gaseous reaction?
- Kp = 1 / Kc always, because partial pressure is the reciprocal of concentration in every case
- Kp = Kc only when the reaction has no gas, since the gas terms then cancel in the expression
- Kp = Kc always, regardless of the change in gas moles, because the two constants are identical
- Kp = Kc(RT)^change in moles of gas, with R and T in the appropriate units
-
For the equilibrium 2NO(g) + O2(g) ⇌ 2NO2(g), what is the expression for Kp?
- Kp = p(NO)^2 x p(O2) / p(NO2)^2
- Kp = p(NO2)^2 / (p(NO)^2 x p(O2))
- Kp = p(NO2) / (p(NO) x p(O2))
- Kp = p(NO2)^2 / (p(NO) + p(O2))
-
If the total pressure of an equilibrium mixture is 5.0 atm and the mole fraction of a gas is 0.20, what is its partial pressure?
- 5.2 atm
- 25 atm
- 1.0 atm
- 0.20 atm
-
A gas mixture contains 0.40 mol of A and 0.60 mol of B in total. What is the mole fraction of A?
- 0.67
- 0.40
- 0.60
- 1.50
-
For the equilibrium H2(g) + I2(g) ⇌ 2HI(g), what is the expression for Kp?
- Kp = p(H2) x p(I2) / p(HI)^2
- Kp = p(HI)^2 / (p(H2) x p(I2))
- Kp = p(HI) / (p(H2) + p(I2))
- Kp = p(HI)^2 / (p(H2) + p(I2))
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Why are partial pressures usually used for gaseous equilibria in industry?
- They remove the need for temperature control, because partial pressures are unaffected by changes in heat
- They directly relate the pressure of each gas to the position of equilibrium at fixed conditions
- They allow the enthalpy change to be measured directly, without any need for a calorimeter
- They show the mass of catalyst required, since the catalyst amount is calculated from the pressure
-
A mixture at equilibrium at 3.0 atm contains equal mole fractions of two gases. What is the partial pressure of each gas?
- 6.0 atm
- 1.5 atm
- 0.50 atm
- 3.0 atm
-
For a reaction where Kp has units of atm-1, which statement is consistent?
- The number of moles of gaseous products is one more than reactants, so the units become atm to a positive power
- The reaction has no gaseous species, so the Kp value cannot be defined for the equilibrium at all
- The number of moles of gaseous products is one less than the number of moles of gaseous reactants
- The reaction is at zero temperature, which is required for the units of atm-1 to arise
-
What is the expression for Kp for the equilibrium 2SO3(g) ⇌ 2SO2(g) + O2(g)?
- Kp = p(SO3) / (p(SO2) + p(O2))
- Kp = p(SO2)^2 x p(O2) / p(SO3)^2
- Kp = p(SO2) x p(O2) / p(SO3)
- Kp = p(SO3)^2 / (p(SO2)^2 x p(O2))
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