Lesson 4.2.4
4.2.4 Analytical techniques Quiz: OCR Chemistry, Unit 3
20 questions
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Lesson 4.2.4, Analytical techniques: 20 multiple choice questions for the OCR Chemistry (H432), Unit 3: Core organic chemistry, written with Revision Ninja.
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The 20 questions
-
What effect does infrared radiation have on covalent bonds in molecules?
- Ionise completely
- Break heterolytically
- Vibrate more
- Rotate freely
-
Which two absorption peaks in an IR spectrum identify a carboxylic acid?
- C=O and C-H
- C=C and O-H
- O-H and C-N
- C=O and O-H
-
Which broad IR absorption peak is used to identify an alcohol?
- C-H bond peak
- C-O bond peak
- O-H bond peak
- C=O bond peak
-
Which bond causes the IR absorption peak found at approximately 3000 cm⁻¹ in most organic compounds?
- C-C bond
- C=O bond
- C-H bond
- O-H bond
-
What quantity does the mass-to-charge ratio of the molecular ion peak give?
- Molar gas volume
- Relative molecular mass
- Empirical formula mass
- Relative atomic mass
-
A small M+1 peak in a mass spectrum of an organic compound is mainly caused by which isotope?
- Hydrogen-2 (deuterium)
- Carbon-13
- Oxygen-18
- Nitrogen-15
-
Which gas in the atmosphere absorbs infrared radiation through its C-H bonds and contributes to global warming?
- Argon, Ar
- Methane, CH4
- Nitrogen, N2
- Oxygen, O2
-
The molecular ion peak of a compound appears at m/z = 46. What is the relative molecular mass of the compound?
- 47
- 46
- 92
- 45
-
A mass spectrum of an unknown organic compound shows a fragment at m/z = 15. Which ion is most likely responsible?
- CO+
- CH3+
- C2H5+
- COOH+
-
A compound has 6 carbon atoms. Approximately what is the size of its M+1 peak relative to its M peak?
- About 11 per cent
- About 0.6 per cent
- About 6.6 per cent
- About 1.1 per cent
-
A compound is found by elemental analysis to contain 40.0% C, 6.7% H and 53.3% O by mass. What is its empirical formula?
- C2H4O2
- C2H5O
- CH2O
- CHO
-
An IR spectrum has absorptions at 2500–3300 cm⁻¹ and 1710 cm⁻¹. Which functional group is present?
- Ester
- Alcohol
- Aldehyde
- Carboxylic acid
-
A compound with Mr 88 shows a strong IR absorption near 1740 cm^-1 but no broad O-H absorption. Which functional group is most likely present?
- An ester
- A primary alcohol
- A carboxylic acid
- An amine
-
An IR spectrum of a compound shows only a broad absorption between 3200 and 3550 cm^-1 and no C=O absorption. Which type of compound is most likely?
- An alcohol
- An aldehyde
- A carboxylic acid
- A ketone
-
Why can carbon monoxide and nitrogen monoxide pollutants in exhaust fumes be detected using IR spectroscopy?
- Ions scatter radiation
- Gases are coloured
- Bonds absorb IR
- Molecules emit IR
-
A compound has a molecular ion peak at m/z = 58 and a strong IR absorption at about 1715 cm^-1 with no O-H absorption. Which compound fits best?
- Propanone, CH3COCH3
- Propan-1-ol, CH3CH2CH2OH
- Propan-2-ol, CH3CH(OH)CH3
- Propenoic acid, CH2=CHCOOH
-
Which isotope causes the M+1 peak in an organic mass spectrum?
- Carbon-14
- Carbon-12
- Carbon-13
- Hydrogen-2
-
What chemical formula is determined directly from elemental analysis percentage data?
- Molecular formula
- Displayed formula
- Empirical formula
- Structural formula
-
Which wavenumber range is typical for the C=O absorption in an IR spectrum?
- About 1680-1750 cm^-1
- About 3200-3550 cm^-1
- About 600-800 cm^-1
- About 2100-2260 cm^-1
-
A compound contains 85.7% carbon and 14.3% hydrogen by mass. What is its empirical formula?
- C2H4
- CH
- CH2
- C3H7
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