Lesson 3.3.6.3
3.3.6.3 Infrared spectroscopy Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.6.3, Infrared spectroscopy: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
-
In an infrared spectrum, what unit is used for the absorption position?
- mol dm-3, the unit of concentration used for solutions in titration
- m/z, the mass-to-charge ratio recorded in mass spectrometry for ions
- ppm, the unit of chemical shift on the delta scale used in NMR
- cm-1 (wavenumber)
-
Which bond gives a strong absorption around 1680-1750 cm-1?
- C-H
- O-H in alcohols
- N-H in amines
- C=O
-
Which absorption indicates an alcohol O-H group?
- A sharp absorption at about 1650 cm-1
- A broad absorption at about 3200-3550 cm-1
- A sharp absorption at about 1720 cm-1
- A strong absorption at about 1000 cm-1 only
-
What is the main use of the fingerprint region of an infrared spectrum?
- Measuring the molar mass of the sample from the height of its tallest peak
- Finding the number of carbon atoms directly from the position of each band
- Measuring the concentration of a solution by comparing absorbance with a standard
- Comparing the spectrum with a reference to identify the molecule
-
Which gas in the atmosphere absorbs infrared radiation and contributes to global warming?
- Nitrogen, which is diatomic and absorbs only in the ultraviolet region strongly
- Carbon dioxide
- Argon, which is a noble gas and does not vibrate, so it cannot absorb infrared
- Oxygen, which is diatomic and forms a weak greenhouse effect in the stratosphere
-
A spectrum shows a very broad absorption between 2500 and 3300 cm-1 and a sharp absorption near 1710 cm-1. Which group is most likely present?
- Carboxylic acid
- Alcohol, which shows a broad O-H band but no C=O band in the spectrum
- Alkene, which shows a C=C band near 1650 but no O-H or C=O band
- Amine, which shows N-H bands near 3300-3500 but no C=O band in the spectrum
-
Which feature distinguishes ethanol from ethanal in an infrared spectrum?
- Ethanal shows a broad O-H absorption at 3200-3550 cm-1 that ethanol lacks
- Ethanol shows a C=O absorption at 1720 cm-1 that ethanal lacks
- Ethanol shows a broad O-H absorption at 3200-3550 cm-1 that ethanal lacks
- Ethanal shows a C=C absorption at 1650 cm-1 that ethanol lacks
-
Which wavenumber range is characteristic of a C=O stretch?
- 3200-3550 cm-1
- 1620-1680 cm-1
- 2850-3300 cm-1
- 1680-1750 cm-1
-
Which bond gives absorptions in the range 2850-3300 cm-1 in almost every organic compound?
- C-H
- N-H in primary amines only
- C=O
- C=C
-
A sample of propanone is suspected of containing water. Which infrared feature would reveal this?
- A sharp absorption around 1650 cm-1
- A broad absorption around 3200-3550 cm-1
- A sharp absorption around 1715 cm-1
- A strong absorption around 1000 cm-1
-
A spectrum shows an absorption at about 1650 cm-1 but none at 1700-1750 cm-1. Which bond is most likely present?
- O-H
- C=O
- C-O
- C=C
-
Which statement distinguishes an amine N-H absorption from an alcohol O-H absorption?
- N-H absorbs more sharply, around 3300-3500 cm-1, than the broad alcohol O-H band
- N-H and O-H absorb at exactly the same wavenumber and cannot be separated
- N-H absorbs at 1000 cm-1 while O-H absorbs at 3300 cm-1
- N-H absorbs at 1700 cm-1 while O-H absorbs at 1650 cm-1
-
Two isomers both show a C=O absorption near 1720 cm-1. Which isomer shows a very broad absorption between 2500 and 3300 cm-1?
- The carboxylic acid
- The aldehyde, which shows a sharp C=O band near 1725 and a C-H band near 2720
- The ester, which shows a sharp C=O band near 1735 but no broad O-H band
- The ketone, which shows a sharp C=O band near 1715 but no broad O-H band
-
Why does carbon dioxide in the atmosphere contribute to global warming, in infrared terms?
- Its bonds absorb infrared radiation emitted from Earth and re-emit it, trapping heat
- Its bonds reflect all visible light back into space, so less heat reaches the surface
- Its bonds convert infrared radiation into ultraviolet radiation that heats the atmosphere
- Its bonds block all sunlight from reaching the surface, cooling the lower atmosphere
-
Why are nitrogen and oxygen not significant greenhouse gases?
- They are diatomic and do not change dipole moment on vibration, so they absorb little infrared
- They absorb strongly only in the ultraviolet region, so they do not trap infrared
- They react with carbon dioxide to remove its infrared absorption from the air
- They are too heavy to rise into the upper atmosphere where infrared is absorbed
-
A compound shows a strong absorption at 1715 cm-1 and no broad O-H absorption, with formula C3H6O. Which compound is most likely?
- Propenoic acid
- Propan-1-ol
- Propanone
- Propene
-
Which compound shows a C=O absorption near 1735 cm-1 and no broad O-H absorption?
- Ethanoic acid
- Ethyl ethanoate
- Ethanol
- Ethanamine
-
What must a student use alongside an infrared spectrum to identify functional groups?
- A solubility table for ionic compounds, which does not list infrared absorptions
- The Periodic Table of relative atomic masses only, which gives no bond information
- The Chemistry Data Sheet or Booklet table of characteristic absorptions
- A table of standard electrode potentials, which relates to redox reactions only
-
Which wavenumber range is characteristic of a C-O single bond stretch?
- 1620-1680 cm-1
- 2850-3300 cm-1
- 3200-3550 cm-1
- 1000-1300 cm-1
-
An infrared spectrum shows a strong absorption at 1700-1750 cm-1 and a band at 1000-1300 cm-1, with no broad O-H band. Which functional group is most likely?
- Alkene
- Ester
- Amine
- Alcohol
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