Lesson 3.3.12.2
3.3.12.2 Biodegradability and disposal of polymers Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.12.2, Biodegradability and disposal of polymers: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
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How are polyesters and polyamides broken down in the environment?
- By reduction with hydrogen gas over a nickel catalyst, which removes the ester links
- By hydrolysis of their ester or amide linkages
- By polymerisation into larger chains through free-radical addition of the monomers
- By oxidation to carbon dioxide only, which leaves no solid residue in the soil
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Which is a key advantage of recycling polymers?
- It increases the amount of fossil fuel needed, because the plastic must be remade each time
- It removes the need for any sorting of waste, so every item can be processed together
- It always produces a more toxic product, which is why it is avoided by most councils
- It conserves raw materials and reduces the amount of waste sent to landfill
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What is a disadvantage of disposing of polymers in landfill sites?
- Landfill converts polymers into metal ions that dissolve into groundwater supplies
- Landfill releases oxygen into the atmosphere, which speeds up the breakdown of waste
- Non-biodegradable polymers take up space and persist for a very long time
- Landfill removes all carbon from the polymer, leaving only inert mineral residue behind
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Which disposal method may release toxic gases such as hydrogen chloride from some polymers?
- Incineration
- Recycling
- Anaerobic digestion
- Composting
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Why can polyesters be hydrolysed while polyalkenes cannot?
- Polyesters contain only C=C double bonds, which react readily with water in soil and sunlight
- Polyalkenes contain ester linkages that are unreactive, so water cannot break them down in soil
- Polyesters contain ester linkages that water can attack, while polyalkene C-C bonds are not attacked by water
- Polyesters contain only C=C double bonds that react with water, while polyalkenes have ester links
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Which factor makes polyalkenes chemically resistant to breakdown?
- Ionic bonds between the monomer units
- Strong, non-polar C-C and C-H bonds in the backbone
- Weak hydrogen bonds between the chains
- Easily hydrolysed ester groups along the chain
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What is the product of hydrolysing nylon 6,6 completely?
- Propane-1,2,3-triol and sodium ethanoate
- Hexanedioic acid and 1,6-diaminohexane
- Ethene and propene
- Ethane-1,2-diol and benzene-1,4-dicarboxylic acid
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Which bond is broken when a polyamide is hydrolysed?
- The C-C bond in the backbone
- The C-H bond on the chain
- The amide C(=O)-N bond
- The C=C double bond in the chain
-
Which statement about biodegradable polymers is correct?
- They are unaffected by water and sunlight at all times, so they never degrade
- They can only be broken down in a laboratory furnace at very high temperature
- They are broken down by microorganisms or environmental hydrolysis into smaller molecules
- They cannot be hydrolysed because they contain no bonds that water could attack
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Which disposal method best balances resource use and environmental impact for polyesters?
- Storing in sealed containers for ever, which avoids any environmental release at all
- Recycling, possibly by hydrolysis back to monomers
- Dumping in the sea without any treatment, which is the cheapest way to dispose of it
- Burning without energy recovery, which releases the gases straight into the air
-
Which polymer would be expected to break down by hydrolysis in damp soil?
- Polystyrene
- Polyethene
- Polyester
- Polypropene
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Why is hydrolysing polyester back to its monomers useful for recycling?
- Hydrolysis removes all carbon from the polymer
- The monomers are impossible to purify
- The monomers are always toxic and must be burned
- The monomers can be reused to make new polymer
-
Which statement about addition polymers and disposal is correct?
- Addition polymers readily hydrolyse in water at room temperature
- Addition polymers can only be disposed of by fermentation
- Addition polymers are always made from amino acids
- Most addition polymers are non-biodegradable and persist in the environment
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Which product forms when Terylene is fully hydrolysed?
- Hexanedioic acid and 1,6-diaminohexane, which are the monomers of nylon 6,6 polymer
- Propanoic acid and ethanol, which are the products of hydrolysing a simple ester
- Benzene-1,4-dicarboxylic acid and ethane-1,2-diol
- Ethene and oxygen, which are the products of burning a polyalkene in excess air
-
What is a disadvantage of recycling mixed plastics?
- Recycling always increases the amount of landfill waste that must be collected
- Recycling removes all ester groups from the plastic, leaving a useless residue behind
- Mixed plastics cannot be heated at all, so they must always go to landfill instead
- The different polymers must be sorted, and contamination can reduce the quality of the recycled product
-
Which disposal method recovers energy from polymer waste?
- Incineration with energy recovery
- Landfill with no treatment, which keeps the waste compact but releases leachate
- Dumping in rivers, which is an easy but harmful way of removing the waste from sight
- Storage in open ponds, which allows the polymer to weather and break down slowly
-
What is the main advantage of incineration of polymer waste?
- It recovers energy from the waste
- It makes all polymers biodegradable
- It produces no gases at all
- It returns the monomers to their original form
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Which statement about biodegradability is INCORRECT?
- Polyesters are biodegradable because they can be hydrolysed
- Polyamides can be hydrolysed in the environment
- Polyalkenes persist in landfill for long periods
- Polyalkenes are biodegradable because they hydrolyse easily
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Which structural feature is the main factor that determines whether a polymer is biodegradable?
- The presence of benzene rings in side chains, which give the polymer its rigidity
- The presence of hydrolysable linkages such as ester or amide groups in the backbone
- The number of carbon atoms in one monomer only, which sets the length of the chain
- The colour of the polymer, which controls how fast it absorbs sunlight in the soil
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Which polymer gives only carbon dioxide and water on complete combustion?
- Polyvinyl chloride, PVC, which releases hydrogen chloride and other harmful gases on burning
- Polyethene with added chlorine, which gives hydrogen chloride and carbon monoxide on burning
- A polyester made only from C, H and O atoms
- Nylon 6,6, which contains nitrogen and so gives toxic nitrogen oxides when burned in air
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