Lesson 3.3.11.2
3.3.11.2 Base properties Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.11.2, Base properties: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
-
What property of amines makes them act as bases?
- The C-N bond can donate a pair of electrons to carbon
- The lone pair of electrons on nitrogen can accept a proton
- They have a negative charge on nitrogen
- They contain a delocalised pi system
-
Which amine is the strongest base in the specification comparison?
- Phenylamine
- Benzene-1,3-diamine
- Ammonia
- Ethylamine
-
Why is phenylamine a weaker base than ethylamine?
- The lone pair on nitrogen is delocalised into the benzene ring, so it is less available to accept a proton
- The benzene ring removes all lone pairs from nitrogen, so no protonation can happen
- Phenylamine contains more hydrogen atoms per molecule, which makes it less basic overall
- Phenylamine is a stronger acid than ethylamine, so it donates protons more readily
-
Why is ethylamine a stronger base than ammonia?
- The ethyl group donates electron density to nitrogen, making its lone pair more available
- Ethylamine contains a carbon-carbon double bond that accepts protons from the solution
- The ethyl group removes electron density from nitrogen, making its lone pair less available
- Ammonia contains no lone pair on nitrogen, so it cannot accept protons at all
-
Which order lists the bases from strongest to weakest?
- Propylamine > ammonia > phenylamine
- Phenylamine > ammonia > propylamine
- Ammonia > propylamine > phenylamine
- Propylamine > phenylamine > ammonia
-
Which species is formed when ammonia accepts a proton?
- NH3+
- NH2+
- NH2-
- NH4+
-
What is the salt formed when methylamine reacts with hydrogen chloride?
- Methylammonium nitrate, CH3NH3+ NO3-
- Methylammonium chloride, CH3NH3+ Cl-
- Methyl chloride, CH3Cl
- Methanamide, HCONH2
-
Which ion makes an aqueous solution of an amine alkaline?
- Hydrogen carbonate ion, HCO3-
- Hydrogen ion, H+
- Hydroxide ion, OH-
- Chloride ion, Cl-
-
What is the relationship between pKb and base strength?
- A higher pKb means a stronger base
- pKb is unrelated to base strength
- A higher pKb means a weaker base
- pKb measures only the molar mass of a base
-
Which amine has the lowest pKb value among ethylamine, ammonia and phenylamine?
- Ammonia
- Phenylamine
- Ethylamine
- All three have equal pKb values
-
Which factor makes the lone pair of an amine more available for protonation?
- Electron-donating alkyl groups
- Replacement of N with a carbon atom
- Delocalisation into a benzene ring
- Strong electron withdrawal by a carbonyl group
-
What is the product when phenylamine is protonated by a strong acid?
- Phenol and hydrogen, formed when the amine is oxidised by the strong acid present
- Nitrobenzene and water, formed when the amine is oxidised back to the nitro compound
- The phenylammonium ion, C6H5NH3+
- Benzene and ammonia, formed when the ring is protonated and loses its substituent
-
What is the conjugate acid of ethylamine?
- CH3CH2NH4+
- CH3CH2NH3+
- CH3CH2NH-
- CH3CH2NH2+
-
Which statement describes an amine as a Bronsted-Lowry base?
- It accepts a proton
- It donates a proton
- It releases hydroxide ions in its own structure
- It accepts an electron pair from a carbon atom
-
Which solution would have the higher pH: 0.1 mol dm-3 ethylamine or 0.1 mol dm-3 phenylamine?
- Phenylamine
- Neither solution is basic
- Ethylamine
- They would have the same pH
-
Which species is the conjugate base of CH3NH3+?
- CH3NH2
- CH3NH4
- CH3NH-
- CH3NH3-
-
Which of these is the stronger base: cyclohexylamine or phenylamine?
- Phenylamine
- They are equally basic
- Cyclohexylamine
- Neither is a base
-
What mass of HCl is needed to neutralise 0.05 mol of ethylamine?
- 0.91 g
- 1.83 g
- 0.18 g
- 3.65 g
-
Which conjugate acid is the strongest acid?
- Methylammonium ion, CH3NH3+
- Ethylammonium ion, CH3CH2NH3+
- Ammonium ion, NH4+
- Phenylammonium ion, C6H5NH3+
-
Which description best defines a weak base?
- It is a salt that contains no lone pair, so it cannot accept any protons at all
- It is a metal hydroxide that dissolves fully to give a high concentration of OH-
- It is only partially protonated when it dissolves in water
- It is completely protonated in water, so it gives a strong alkaline solution
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