Lesson 3.1.5.2
3.1.5.2 Maxwell–Boltzmann distribution Quiz: AQA Chemistry, Unit 1
20 questions
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Lesson 3.1.5.2, Maxwell–Boltzmann distribution: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.
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The 20 questions
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What does a Maxwell-Boltzmann distribution show?
- The bond enthalpies of molecules in the gas, averaged over all the bonds present
- The spread of molecular energies in a gas at a given temperature
- The pressure of a gas in a flask, measured at a fixed temperature and volume
- The atomic masses of the elements present in the gas sample at the given temperature
-
On a Maxwell-Boltzmann curve, what is plotted on the x-axis?
- Volume of the container
- Pressure
- Molecular energy
- Mass of the gas
-
On a Maxwell-Boltzmann curve, what is plotted on the y-axis?
- The activation energy of the reaction in kJ per mole
- The number or fraction of molecules with that energy
- The temperature of the gas on the kelvin scale
- The mass of the molecules in the gas sample
-
How does the peak of a Maxwell-Boltzmann curve change when the temperature rises?
- It moves to the left and becomes taller and narrower
- It stays in the same place, with only its height changing
- It moves to the right and becomes lower and broader
- It disappears completely as the gas heats up in the flask
-
Which region of a Maxwell-Boltzmann curve shows molecules with energy at or above the activation energy?
- The start of the curve at zero energy, where the molecules are at rest
- The area to the left of zero energy, which is always empty on the curve
- The height of the peak only, which shows the most common energy in the sample
- The area to the right of the activation energy line
-
What does the total area under a Maxwell-Boltzmann curve represent?
- The pressure of the gas
- The total mass of the molecules
- The total activation energy
- The total number of molecules
-
Which statement about a Maxwell-Boltzmann curve at a fixed temperature is true?
- It is symmetric about the origin
- It has no peak
- It starts at the origin and levels off at high energy
- It starts at a non-zero value at zero energy
-
At 400 K compared with 300 K, which statement about the average molecular energy is correct?
- The average energy is higher at 300 K
- The energies are equal at both temperatures
- Temperature has no effect on molecular energy
- The average energy of molecules is higher at 400 K
-
At a higher temperature, how does the fraction of molecules above the activation energy change?
- It is zero
- It is smaller than at the lower temperature
- It is equal to the lower temperature
- It is greater than at the lower temperature
-
Which change to temperature increases the number of molecules with energy above the activation energy?
- Lowering the temperature
- Raising the temperature
- Reducing the volume only
- Removing some of the gas
-
At a higher temperature, which description of the curve is correct?
- The curve has the same shape
- The curve shrinks to zero
- The peak is higher and shifted to lower energy
- The peak is lower and shifted to higher energy
-
What does a shift of the Maxwell-Boltzmann curve to the right mean?
- The number of molecules has increased
- The average molecular energy has decreased
- The average molecular energy has increased
- The pressure of the gas has fallen to zero
-
Which statement about molecular energies in a gas is correct?
- Only the fastest molecules have any energy
- The energy distribution does not depend on temperature
- Molecules have a range of energies, not all the same
- All molecules have exactly the same energy
-
What is true of the areas under Maxwell-Boltzmann curves at two different temperatures for the same sample?
- They are greater at the higher temperature, because more molecules gain energy
- They are equal, because the total number of molecules is the same
- They are zero for both temperatures, because the area only shows the energy barrier
- They are smaller at the higher temperature, because molecules spread across more energies
-
Why does the Maxwell-Boltzmann curve have a long tail at high energies?
- All molecules move at identical speeds, so the tail is produced by measurement error alone
- The gas is ionised at high energies, so the tail shows where charged particles form
- The temperature is zero at the far end of the tail, so the molecules have no motion
- A few molecules have much higher energies because of random collisions
-
Why is the peak of the curve lower and broader at a higher temperature, even though the total area is the same?
- More molecules are produced at a higher temperature, so the whole curve grows larger in area
- Molecules lose mass at high temperature, so the distribution spreads out across the chart
- Molecules are spread over a wider range of energies, so the same number is spread out
- The gas volume decreases at high temperature, so the molecules are squeezed into a narrower band
-
Why does a small temperature rise often produce a large change in the number of molecules above the activation energy?
- The number of molecules doubles for each degree of temperature rise in the closed flask
- The average energy rises by a large factor, so every molecule gains enough energy to react
- The high-energy tail is sensitive to temperature, so a small rise moves many molecules above the activation energy
- Activation energy depends linearly on temperature, so it rises with every degree of heating
-
What happens to a gas's distribution curve if its temperature is halved?
- The peak moves to higher energy, so the molecules gain more energy as the gas cools
- The curve disappears completely, because the molecules stop moving at half temperature
- The peak moves to lower energy and the curve becomes taller and narrower
- The curve becomes broader and flatter, so the molecules spread out across more energies
-
A reaction's activation energy is lowered at the same temperature. What happens to the area under the curve to the right of the activation energy line?
- It becomes zero
- It decreases, so fewer molecules react
- It increases, so more molecules have energy above the activation energy
- It stays the same because the total number of molecules is constant
-
Two gas samples at the same temperature have different molar masses. Which statement is correct?
- Heavier molecules always have higher kinetic energy, so they reach the activation energy first
- Molar mass changes the activation energy, so the heavier gas always needs more energy to react
- Lighter molecules never have a distribution curve, because they are too fast to measure
- Heavier molecules move more slowly, but at the same temperature they have the same average kinetic energy
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