Lesson 3.1.12.5
3.1.12.5 pH curves, titrations and indicators Quiz: AQA Chemistry, Unit 1
20 questions
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Lesson 3.1.12.5, pH curves, titrations and indicators: 20 multiple choice questions for the AQA Chemistry (7405), Unit 1: Physical chemistry, written with Revision Ninja.
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The 20 questions
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What is the pH at the equivalence point of a strong acid titrated with a strong base?
- Greater than 7, because the salt formed is basic
- 7
- Less than 7, because the salt formed is acidic
- Exactly 1, because the strong acid remains
-
What is the pH at the equivalence point of a weak acid titrated with a strong base?
- Less than 7, because the weak acid is still present
- Exactly 7, because all titrations give pH 7
- Greater than 7, because the salt formed is basic
- Exactly 1, because only the acid is in the flask
-
What is the pH at the equivalence point of a strong acid titrated with a weak base such as ammonia?
- Exactly 14, because ammonia is a base
- Greater than 7, because the salt formed is basic
- Exactly 7, because all titrations give pH 7
- Less than 7, because the salt formed is acidic
-
What is a vertical section of a pH curve?
- A region where the pH stays almost constant as acid is added
- A rapid change in pH around the equivalence point
- The pH at which the indicator changes colour at the start
- The starting pH of the solution before any titrant is added
-
What is the best indicator for titrating a weak acid with a strong base?
- Bromothymol blue, whose range lies entirely below pH 4 for every titration
- Phenolphthalein, whose colour change range of about 8.2 to 10 lies on the steep part of the curve
- Any indicator, because the pH curve is the same for all acids and bases
- Methyl orange, whose colour change range of about 3.1 to 4.4 lies on the steep part of the curve
-
Which indicator is most suitable for titrating a strong acid with a weak base such as ammonia?
- Phenolphthalein, because phenolphthalein changes colour in strong acid only
- Any indicator, because the pH of the equivalence point is always 14
- Methyl orange, whose colour change range of about 3.1 to 4.4 matches the acidic equivalence point
- Phenolphthalein, whose colour change range of about 8.2 to 10 matches the acidic equivalence point
-
25.0 cm^3 of 0.100 mol dm^-3 NaOH is titrated with 0.0500 mol dm^-3 HCl. What volume of HCl is needed to reach the equivalence point?
- 50.0 cm^3
- 100 cm^3
- 25.0 cm^3
- 12.5 cm^3
-
20.0 cm^3 of 0.200 mol dm^-3 HCl is neutralised by 0.100 mol dm^-3 NaOH. What volume of NaOH is needed?
- 40.0 cm^3
- 80.0 cm^3
- 10.0 cm^3
- 20.0 cm^3
-
25.0 cm^3 of ethanoic acid is titrated with 0.100 mol dm^-3 NaOH, and 22.5 cm^3 is needed to reach the equivalence point. What is the concentration of the acid?
- 0.100 mol dm^-3
- 0.0900 mol dm^-3
- 0.0450 mol dm^-3
- 0.225 mol dm^-3
-
What is the pH of a 0.10 mol dm^-3 strong acid at the start of its titration with a strong base?
- 0.10
- 13.0
- 1.0
- 7.0
-
Why does a weak acid titration curve start at a higher pH than a strong acid of the same concentration?
- The weak acid contains more H+ ions than the strong acid at the same concentration
- The weak acid has a higher concentration of OH- ions at the start
- The weak acid does not dissociate at all, so its pH is the same as pure water
- The weak acid is only partly dissociated, so it has a lower [H+] at the start
-
Why does the pH at the equivalence point of a weak acid titration not equal 7?
- The salt formed is strongly acidic, because weak acids always produce acidic salts
- The salt formed hydrolyses to give an excess of OH^- ions, so the solution is basic
- Water is consumed completely in the reaction, leaving no solvent to set the pH
- The equivalence point is always at pH 14, whatever the acid used
-
A monoprotic acid solution of 25.0 cm^3 requires 20.0 cm^3 of 0.0250 mol dm^-3 NaOH to reach the equivalence point. What is the concentration of the acid?
- 0.0250 mol dm^-3
- 0.0400 mol dm^-3
- 0.0100 mol dm^-3
- 0.0200 mol dm^-3
-
What volume of 0.10 mol dm^-3 NaOH neutralises 10.0 cm^3 of 0.050 mol dm^-3 nitric acid?
- 20.0 cm^3
- 10.0 cm^3
- 2.5 cm^3
- 5.0 cm^3
-
Why does a strong acid and strong base curve show a larger pH change at the equivalence point than a weak acid and strong base curve?
- The strong acid is fully dissociated, so the pH changes more sharply near the equivalence point
- The weak acid has a higher concentration of H+ ions, which buffers the pH change
- The weak acid is fully dissociated, so the pH changes more sharply near the equivalence point
- The strong base is only partly dissociated, so the pH changes less sharply
-
Which statement about the choice of indicator in a titration is correct?
- An indicator should change colour within the steep vertical part of the pH curve at the equivalence point
- An indicator should change colour at pH 7 in every titration, whatever the acid and base
- An indicator should change colour at the very start of the titration, before any reagent is added
- An indicator should be a strong acid, so that it dissociates fully in the flask
-
Which combination of acid and base gives an equivalence point at pH 7?
- Ethanoic acid and sodium hydroxide
- Ethanoic acid and ammonia
- Hydrochloric acid and ammonia
- Hydrochloric acid and sodium hydroxide
-
What is the purpose of a pH curve in an acid-base titration?
- To show how pH changes as titrant is added, so that a suitable indicator can be chosen
- To show the number of electrons transferred during the titration
- To show the rate at which the acid and base react with each other
- To show the enthalpy change of the neutralisation reaction at each point
-
On the pH curve of a weak acid titrated with a strong base, where is the half-equivalence point?
- At the start of the titration, where the pH equals 7, before any of the titrant has been added to the flask
- At half the volume needed to reach the equivalence point, where pH equals pKa of the weak acid
- At the equivalence point itself, where the pH equals 14, because the weak acid has been fully neutralised by base
- At twice the volume of the equivalence point, where the pH equals 1, because excess strong acid is then present
-
Where is the equivalence point located on a pH curve?
- At the flat region at the top of the curve, where pH stays constant
- At the very start of the curve, before any titrant is added
- At the centre of the steep vertical section, where moles of acid and base are equal
- At the end of the curve, when all the titrant has been used up
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