Lesson 2A.5
2A.5 Solvents and metallic bonding Quiz: Pearson Edexcel Chemistry, Unit 2
20 questions
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Lesson 2A.5, Solvents and metallic bonding: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 2: Bonding and Structure, written with Revision Ninja.
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The 20 questions
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What is metallic bonding?
- The strong electrostatic attraction between metal cations and the delocalised electrons
- The attraction between molecules caused by temporary dipoles that form and disappear in the liquid or solid
- The sharing of electron pairs between two non-metal atoms, which forms a directional covalent bond
- The transfer of electrons from metal atoms to non-metal atoms, which forms oppositely charged ions
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Why does water dissolve sodium chloride?
- Water molecules are ionic and attract the ions
- Sodium chloride reacts chemically with water to form a new compound
- Water molecules break the ions apart into atoms
- Polar water molecules surround and hydrate the Na+ and Cl- ions
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Why does water dissolve ethanol readily?
- Water forms covalent bonds with ethanol
- Ethanol has no intermolecular forces, so it does not separate
- Ethanol is ionic, so it mixes with water
- Ethanol's O-H group forms hydrogen bonds with water molecules
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Why is water a poor solvent for halogenoalkanes?
- Halogenoalkanes are metallic and so do not dissolve in water, which is a molecular liquid with no metal atoms
- Halogenoalkanes react instantly with water to form a gas, so they cannot be dissolved in water at all
- Water molecules are non-polar and repel the polar halogenoalkane molecules that come close to them in solution
- Halogenoalkanes cannot form hydrogen bonds with water molecules
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Which solvent dissolves iodine best?
- Dilute sodium hydroxide
- Aqueous silver nitrate
- Water
- Hexane
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Why are metals good electrical conductors?
- Metals contain ionic bonds that break under a voltage, releasing ions that carry the electric current
- Metal atoms share pairs of electrons in covalent bonds, which can slide along the metal under a voltage
- Metal ions move freely through the lattice and carry charge from one end of the metal to the other
- Delocalised electrons are free to move through the lattice and carry charge
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Why are metals malleable?
- Metal atoms are covalently bonded in sheets that flatten under pressure, so the metal can be hammered thin
- Layers of metal ions can slide over one another while the delocalised electrons stay attached to the whole lattice
- Metal bonds break and reform only when the metal is heated, which allows the atoms to be moved into a new shape
- Metal ions are free to move as in a liquid, so the solid flows into a new shape when it is struck or pressed
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Which metal has stronger metallic bonding: sodium or magnesium?
- Sodium, which has more protons per atom than magnesium, so its nucleus attracts the delocalised electrons more
- Magnesium, which has a larger atomic radius than sodium, so its delocalised electrons are held more strongly
- Magnesium, which has two delocalised electrons per atom and a smaller, more highly charged ion
- Sodium, which has one delocalised electron per atom and a smaller ion, so its metallic bonding is stronger overall
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Which solvent is most likely to dissolve a compound that is soluble in both water and hexane?
- Ethanol, which has an O-H group for hydrogen bonding and a hydrocarbon chain for London forces
- Hexane, which has only ionic attraction between its molecules, so it dissolves any compound that carries a charge
- Sodium chloride solution, which has covalent bonds between its ions, so it dissolves compounds that contain covalent bonds
- Water, which has only hydrogen bonds between its molecules, so it attracts any compound that has a hydrogen atom in it
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A compound dissolves in water but not in hexane. What is its most likely type?
- Ionic or highly polar
- Metallic with delocalised electrons, which dissolve in water as ions and not in the non-polar hexane solvent
- Non-polar covalent with only London forces, which mix readily with hexane but not with the water solution
- Alkane with no polar bonds, which dissolves in hexane easily but is repelled by the polar water molecules
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Why does 1-bromobutane dissolve poorly in water?
- It cannot form hydrogen bonds with water molecules
- It reacts with water to form a gas that escapes from the solution, so it cannot stay dissolved in the water
- It has more hydrogen bonds between its molecules than water does, so it resists mixing with the water
- It is metallic and does not mix with the molecular water, which is made of covalently bonded molecules
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Why does iodine dissolve in hexane but not in water?
- Iodine forms hydrogen bonds with hexane molecules but cannot form them with water molecules at all in solution
- I2 and hexane have similar weak London forces, so they mix, whereas water's hydrogen bonds exclude I2
- Water and iodine react together to form a solid precipitate, which settles out of the solution entirely
- Hexane is ionic, so it attracts iodine atoms strongly and holds them in solution away from the water
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Explain why sodium chloride dissolves in water but not in hexane.
- Water hydrates the ions and its polarity overcomes the lattice, whereas hexane lacks polarity and cannot separate the ions
- Sodium chloride molecules are non-polar and so they dissolve only in non-polar solvents such as hexane
- Hexane forms stronger covalent bonds with the ions than water does, which pulls the ions out of the lattice
- Water has no polarity, so it dissolves ions only by making covalent bonds with them in the solution
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Explain why magnesium is harder than sodium.
- Mg2+ is smaller and more highly charged, and each magnesium atom contributes two delocalised electrons, giving stronger metallic bonding
- Magnesium is covalently bonded, which makes it harder than sodium because covalent bonds are always stronger
- Sodium has delocalised electrons that repel each other more strongly than those in magnesium do in the lattice
- Magnesium has more neutrons than sodium, which pull its positive ions closer together in the metallic lattice
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Why does solid sodium conduct electricity but solid sodium chloride does not?
- Sodium chloride conducts only when its bonds are dissolved in hexane, which frees its charge carriers
- Sodium has covalent bonds that allow the current to pass along them through the solid sample of the metal
- Sodium chloride contains no ions at all in the solid, so there are no charge carriers to conduct the current
- Sodium has delocalised electrons free to move, but in solid NaCl the ions are fixed in the lattice
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Explain why short-chain alcohols dissolve in water but long-chain alcohols do not dissolve well.
- The O-H group forms hydrogen bonds with water, but a long hydrocarbon chain has large non-polar regions that water cannot interact with
- Long-chain alcohols form covalent bonds with water molecules, but these bonds are too weak to dissolve them
- Short-chain alcohols have more protons than long-chain alcohols, which attracts the water molecules towards them
- Long-chain alcohols are ionic and repel water molecules strongly, so they cannot dissolve in water at all
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Explain why molten ionic solids conduct electricity but metals conduct when solid.
- Molten ionic solids contain delocalised electrons that carry the charge, while metals contain fixed ions in the lattice
- Metals conduct only when molten, because the ions break free from the lattice and move through the liquid metal
- Ionic solids conduct because their covalent bonds carry electrons along the bonds between the atoms in the solid
- Molten ionic solids have mobile ions carrying charge, while metals conduct through delocalised electrons that are mobile even in the solid
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Which principle explains why one solvent dissolves a given solute better than another?
- The solute and solvent interact through similar intermolecular forces, which can replace one another
- The solute must be a gas before it can dissolve in any solvent, which is why solids do not dissolve easily
- The solvent must have a higher boiling temperature than the solute so that it can hold the solute in solution
- The solvent must contain metal ions in order to dissolve the solute, which provides the attraction needed for dissolving
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What explains why a dissolved ionic compound conducts electricity?
- It forms metallic bonds with the solvent molecules, which allow the solution to carry electric charge easily
- Its molecules are polar, so they carry charge as dipoles that move through the solution to the electrodes
- Its ions are free to move in solution and carry charge to the electrodes
- Its electrons are delocalised across the whole solution, so they can carry the current from one electrode to the other
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Which property of metals is best explained by delocalised electrons?
- Electrical conductivity in the solid state
- Low melting temperature, which is caused by the weak forces between the molecules in the metal
- Solubility in hexane, which occurs because the metal atoms form non-polar covalent molecules
- Brittleness under stress, which occurs because the delocalised electrons break the lattice apart
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